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Sunder, S.; Shoeshmith, D.W.; Christensen, H.C.
Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)2003
Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)2003
AbstractAbstract
[en] The concept of geological disposal of used nuclear fuel in corrosion resistant containers is being investigated in several countries. In the Canadian Nuclear Fuel Waste Management Program (CNFWMP), it is assumed that the used fuel will be disposed of in copper containers. Since the predicted lifetimes of these containers are very long (>106 years), only those containers emplaced with an undetected defect will fail within the period for which radionuclide release from the fuel must be considered. Early failure could lead to the entry of water into the container and subsequent release of radionuclides. The release rate of radionuclides from the used fuel will depend upon its dissolution rate. The primary mechanism for release will be the corrosion of the fuel driven by radiolytically-produced oxidants. The studies carried out to determine the effects of water radiolysis on fuel corrosion are reviewed, and some of the procedures used to predict corrosion rates of used fuel in failed nuclear waste containers described. (author)
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2003; 17 p; 48 refs., 3 figs. Presented at the NACE Northern Area Eastern Conference, Ottawa, Ontario, September 15-17, 2003.
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