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[en] There are various scientific applications, from astronomical observations to free electron lasers, that make use of X-ray semiconductor detectors like PNCCDs. The PNCCD is a pixelized semiconductor detector for simultaneous X-ray imaging and spectroscopy. For the seven PNCCD cameras of the eROSITA space telescope, a radiation entrance window including an on-chip optical blocking filter has been designed. The blocking filter is a necessity to minimize electron generation by visible light and UV radiation affecting X-ray spectroscopy. A PNCCD with such a blocking filter has not been used so far in astronomy. The following work deals with the analysis of the response of PNCCDs with on-chip filter. This includes the study of photon absorption and emission processes as well as the transport of electrons inside the detector entrance window. Furthermore it comprises the experimental characterization of the detector properties regarding the attenuation of light as well as their X-ray spectral redistribution function and quantum efficiency. With the ability to reveal the involved physical processes, the PNCCD is subject of analysis and measurement device at the same time. In addition to the results of the measurements, simulations of the solid state physics inside the detector are presented. A Geant4 Monte-Carlo code is extended by the treatment of charge loss in the entrance window and is verified by comparison with experimental data. Reproducing the chain of processes from photon absorption to charge collection, this work provides a detailed understanding of the formation of PNCCD spectra. The spectral features observed in the measurements are attributed to their point of origin inside the detector volume and explained by the model. The findings of this work allow high precision analysis of spectra of silicon detectors, e.g. of the eROSITA data, based on the presented detailed spectral response model.