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Massit, Hubert
Conservatoire national des arts et metiers, Centre regional associe de Grenoble - C.U.E.F.A. (France); Commissariat a l'Energie Atomique, Centre d'Etudes Nucleaires de Grenoble, Service d'etudes analytiques, Section de recherches et de controles analytiques - DCAEA-SEA-SRCA (France)1987
Conservatoire national des arts et metiers, Centre regional associe de Grenoble - C.U.E.F.A. (France); Commissariat a l'Energie Atomique, Centre d'Etudes Nucleaires de Grenoble, Service d'etudes analytiques, Section de recherches et de controles analytiques - DCAEA-SEA-SRCA (France)1987
AbstractAbstract
[en] This research thesis reports the development of a process and the determination of the conditions for the fixation of insoluble ruthenium compounds on a Z2CN180 stainless steel in a concentrated nitric environment. The original characteristics and results of this research work are the use of a rotating disk to control the hydrodynamic conditions of suspension particle transport towards the collector surface, and the application of X ray spectrometry of solid deposits of ruthenium compounds fixed on this surface. Characterization techniques (granulometry, Auger electron spectroscopy or AES, electron spectroscopy for chemical analysis or ESCA) allowed the assessment of the influence of various parameters (size, surface chemical composition) on the studied process. Electrochemical techniques are used to show the role of particle-substrate Coulomb interactions, on the quantity of fixed particles and on fixation kinetics. The author evokes possible developments and applications, notably decontamination processes
[fr]
Cette etude a permis d'etablir le processus et de decouvrir les conditions de fixation de composes insolubles du ruthenium sur l'acier inoxydable Z2CN1810 en milieu nitrique concentre. L'originalite et l'aboutissement de ces investigations reposent essentiellement sur l'utilisation d'un systeme a disque tournant permettant de maitriser les conditions hydrodynamiques de transport des particules de la suspension vers la surface collectrice et sur l'application de la spectrometrie des rayons X au dosage des depots solides de composes de ruthenium fixes sur cette surface. L'emploi de techniques de caracterisation physiques et physicochimiques (analyse granulometrique, AES et ESCA) a permis d'apprecier l'influence de divers parametres (taille, composition chimique superficielle) sur le processus etudie. L'utilisation de techniques electrochimiques (microelectrophorese, potentiometrie sous courant nul, voltamperometrie a balayage en tension, polarisation) a permis de montrer le role important joue par les interactions coulombiennes particule-substrat, sur la quantite de particules fixees et sur la cinetique de fixation. L'etablissement d'une correlation entre l'allure des courbes cinetiques de fixation, l'evolution morphologique des depots et le regime de transport des particules, nous a conduit a proposer un processus de fixation resultant de la succession de deux phases dont les cinetiques differentes sont regies par des regimes de transport de particules differents (diffusion, convection). Les resultats de cette etude ouvrent de nombreuses perspectives de recherches parmi lesquelles nous suggerons: - la caracterisation physicochimique des surfaces dans le but de mettre en evidence les points d'adherence preferentiels, - l'etude de la mise en oeuvre de procedes d'inhibition de la fixation ou de procedes de decontamination. (auteur)Original Title
Etude du processus de fixation du ruthenium sur l'acier inoxydable en milieu nitrique concentre
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Source
11 Feb 1987; 118 p; 100 refs.; Available from the INIS Liaison Officer for France, see the 'INIS contacts' section of the INIS website for current contact and E-mail addresses: http://www.iaea.org/inis/contacts/; Diplome d'ingenieur C.N.A.M. en electrochimie
Record Type
Report
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Thesis/Dissertation
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ADHESION, CHEMICAL COMPOSITION, CHEMICAL REACTION KINETICS, CONTAMINATION, COULOMB FIELD, DECONTAMINATION, DISSOLUTION, ELECTROPHORESIS, ELUTRIATION, MICROSTRUCTURE, NITRIC ACID, NUCLEAR FUELS, POLARIZATION, REPROCESSING, ROTATING DISK REMOVAL SYSTEMS, RUTHENIUM, SOLIDIFICATION, STAINLESS STEELS, STEEL-CR18NI10-L, X-RAY SPECTROSCOPY
ALLOYS, AUSTENITIC STEELS, CARBON ADDITIONS, CHROMIUM ALLOYS, CHROMIUM-NICKEL STEELS, CLEANING, CORROSION RESISTANT ALLOYS, ELECTRIC FIELDS, ELEMENTS, ENERGY SOURCES, EQUIPMENT, FUELS, HEAT RESISTANT MATERIALS, HEAT RESISTING ALLOYS, HIGH ALLOY STEELS, HYDROGEN COMPOUNDS, INORGANIC ACIDS, INORGANIC COMPOUNDS, IRON ALLOYS, IRON BASE ALLOYS, KINETICS, LOW CARBON-HIGH ALLOY STEELS, MATERIALS, METALS, NICKEL ALLOYS, NITROGEN COMPOUNDS, OXYGEN COMPOUNDS, PHASE TRANSFORMATIONS, PLATINUM METALS, POLLUTION CONTROL EQUIPMENT, REACTION KINETICS, REACTOR MATERIALS, REFRACTORY METALS, SEPARATION PROCESSES, SPECTROSCOPY, STAINLESS STEELS, STEELS, TRANSITION ELEMENT ALLOYS, TRANSITION ELEMENTS
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