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AbstractAbstract
[en] The problems of chemical pollution of water have become a major concern and a priority for the nuclear industry. The aim of this work is to study some ion exchangers used for the removal of strontium ions because 90Sr is one of a major pollutant in nuclear liquid wastes. This study allows linking the physical and chemical properties of these materials and their sorption properties. This work presents therefore the synthesis of two materials - sodium nona-titanate and zeolite A - selected for their specific sorption properties of strontium: A second part of this work is dedicated to the study of specific exchange capacities of these materials for the strontium in presence of other elements such as sodium and calcium. Batch experiments were performed and kinetic and ion exchange models have been applied to understand the selectivity of the materials for strontium removal. Sodium nona-titanate and zeolite A are also studied in actual effluents. Monoliths of zeolite A have been also tested in dynamic ion exchange process. This material is promising for the treatment of radioactive effluents in continuous flow because it joins the sorption properties of the zeolite powder with the advantage of a solid with a macroporous network. (author)
[fr]
Les problemes de pollution chimique de l'eau sont devenus une source de preoccupation importante et un enjeu prioritaire pour les industriels du nucleaire. L'objectif principal de cette these est d'etudier certains mineraux echangeurs ioniques utilisables pour une decontamination liquide en strontium (radioisotope toxique pour l'homme). Mais egalement de relier les proprietes physico-chimiques de ces materiaux avec leurs proprietes de retention du radioisotope. Ce memoire presente donc la synthese de deux materiaux choisis pour leurs proprietes de sorption specifique et quantitative du strontium: le nonatitanate de sodium et la zeolithe A. Une seconde partie du travail est dediee a l'etude des capacites d'echange specifique de ces materiaux vis-a-vis du strontium en presence d'autres elements comme le sodium et le calcium. Le nonatitanate de sodium et la zeolithe A ont egalement ete testes sur des effluents reels. Les performances d'un monolithe de zeolithe A ont ete evaluees pour un procede de traitement en colonne. Ce materiau semble prometteur pour la decontamination d'effluents car il permet de cumuler les avantages de la poudre de zeolithe A avec ceux d'un transfert de matiere sans perte de charge du solideOriginal Title
Etude d'echangeurs d'ions mineraux pour la decontamination liquide en strontium
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Source
26 Jan 2012; 205 p; 106 refs.; Available from the INIS Liaison Officer for France, see the 'INIS contacts' section of the INIS-NKM website for current contact and E-mail addresses: http://www.iaea.org/inis/Contacts/; Chimie Separative Materiaux et Procedes
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Report
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Thesis/Dissertation
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