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Abdel Ghaffar, A.M.; El-Arnaouty, M.B.; Aboulfotouh, M.E.; Taher, N.H.
Proceeding of The Third International on Radiation Sciences and Applications2012
Proceeding of The Third International on Radiation Sciences and Applications2012
AbstractAbstract
[en] Butyl methacrylate and Acrylamide (BMA/AAm) comonomer were grafted onto Low density polyethylene and polypropylene films using direct gamma radiation by grafting technique. The influences of grafting conditions such as solvent, monomer concentration, monomer composition, and irradiation dose on the grafting yield were determined. It was found that, using DMF as a solvent enhanced the copolymerization process. The grafting yield increases with comonomer concentration up to 60 %. . Also it was found that, the degree of grafting of (BMA/AAm) onto LDPE and PP films increases as the AAm content increases till optimum value at (50:50) %. The grafting yield of the comonomer found to be increased with increasing radiation dose. It was observed that the degree of grafting of polyethylene films is higher than that for polypropylene films. Some selected properties of the graft copolymers, such as water uptake and thermal properties determined by using thermogravimetric analysis (TGA) has been carried out. The morphology and structure of grafted films was investigated by using SEM, IR and X-ray diffraction. The improvement in such properties of the prepared copolymers was observed which makes possible uses in some practical applications such as in the removal of some heavy metals from wastewater. It was found that the maximum metal uptake by the copolymer is ordered in the sequence of Cu2+ > CO2+ > Ni2+ ions.
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Egyptian Society of Radiation Sciences and Applications (ESRSA) (Egypt); 920 p; Nov 2012; p. 208-228; ESRSA,12: 3. Conference on Radiation Sciences and Applications; Hurghada (Egypt); 12-16 Nov 2012
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Miscellaneous
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Conference
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AMIDES, CARBOXYLIC ACID SALTS, CHARGED PARTICLES, CHEMICAL ANALYSIS, COHERENT SCATTERING, DIFFRACTION, ELECTROMAGNETIC RADIATION, ELECTRON MICROSCOPY, GRAVIMETRIC ANALYSIS, HYDROGEN COMPOUNDS, IONIZING RADIATIONS, IONS, LIQUID WASTES, MICROSCOPY, ORGANIC COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, ORGANIC POLYMERS, OXYGEN COMPOUNDS, POLYMERS, POLYOLEFINS, QUANTITATIVE CHEMICAL ANALYSIS, RADIATIONS, SCATTERING, THERMAL ANALYSIS, WASTES, WATER
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