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AbstractAbstract
[en] The understanding of degradation mechanism action on the polymer nanocomposites in face of weathering (UV light, heat, acid rain, among others), is the key for development of new additives and new applications. In this work the nanocomposite synthesis was carried in molten state, using twin-screw extruder. The polymer matrix was the HMS-PP (high melt polypropylene) synthesized by gamma irradiation and the nanometric inorganic component was the montmorillonite clay. For better compatibilization between the matrix and clay, it were used maleic anhydride as coupling agent. For environment and in oven accelerated aging assays, the dumbbell samples were prepared under hot pressing. The characterization of clay addition effects and aging effects on the nanocomposites, required the use of techniques of Differential Scanning Calorimetry (DSC), Thermogravimetry (TGA), Fourier Transformed Infrared Spectroscopy (FT-IR), Xray Fluorescence (WDXRF), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and mechanical properties. Samples with 0.1; 1; 3; 5; 10 % of clay were tested. The sample with 5% of clay showed better stability on the environmental assay and accelerated aging in oven assay. On the other hand, the sample with higher percent of clay (10%), was more degraded under on environmental aging than under accelerated aging in stove. In this case, became more resistant until 56 days of assay. On the studied concentrations (less than ≤ 3%) of clay, it can be seen an equilibrium between barrier effect and metallic ions action accelerating the degradative process. (author)
Original Title
Estudo comparativo de nanocompositos de polipropileno modificado sob condicoes de envelhecimento ambiental e acelerado
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Secondary Subject
Source
2016; 158 p; Diss. (M.Sc.)
Record Type
Miscellaneous
Literature Type
Thesis/Dissertation
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Country of publication
CHEMICAL ANALYSIS, CHEMICAL REACTIONS, CLAYS, ELECTROMAGNETIC RADIATION, ELECTRON MICROSCOPY, EVALUATION, GRAVIMETRIC ANALYSIS, INORGANIC ION EXCHANGERS, ION EXCHANGE MATERIALS, IONIZING RADIATIONS, MATERIALS, MICROSCOPY, MINERALS, NANOMATERIALS, NONDESTRUCTIVE ANALYSIS, ORGANIC COMPOUNDS, ORGANIC POLYMERS, POLYMERS, POLYOLEFINS, QUANTITATIVE CHEMICAL ANALYSIS, RADIATIONS, SILICATE MINERALS, SPECTRA, THERMAL ANALYSIS, X-RAY EMISSION ANALYSIS
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