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AbstractAbstract
[en] Bi_2Te_3 single crystals were prepared by the solid-state reaction method. The effect of the vacuum on the growth of Bi_2Te_3 single crystals was studied with varying the oxygen content by controlling the air pressure in the silica tube. High quality Bi_2Te_3 single crystals have been obtained and there is no influence on the growth by an extremely small amount of oxygen in a high vacuum at 1.0 × 10"−"3 Pa. As the air pressure is increased at 1.0 × 10"−"2 Pa, oxygen only mainly impacts on the growth of the surface for the prepared samples. Micron-sized rod-like structure and flower-like clusters are observed on the surface. For the samples prepared at 1.0 × 10"−"1 Pa, x-ray diffraction data show that the yellow part on the surface is Bi_2TeO_5, while the Bi_2Te_3 single crystal is still the major phase as the inside part. More interestingly, various crystal morphologies are observed by scanning electron microscope for Bi_2Te_3 near the boundary between Bi_2Te_3 and Bi_2TeO_5. Possible growth mechanisms for Bi_2Te_3 with different morphologies are discussed in detail. (paper)
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Available from http://dx.doi.org/10.1088/1674-1056/24/7/078101; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
Journal
Chinese Physics. B; ISSN 1674-1056;
; v. 24(7); [5 p.]

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