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Bashir, Aiman K; Tchokonté, Moise B Tchoula; Britz, Douglas; Sondezi, B M; Strydom, André M, E-mail: mtchokonte@uwc.ac.za2015
AbstractAbstract
[en] The results of magnetic susceptibility, χ(T), magnetization, σ(μ_0H), and specific heat, C_P(T), for GdCu_4Au are presented. The room temperature powder X-ray diffraction studies indicate a cubic MgCu_4Sn – type crystal structure with space group F4-bar 3m (No.216). The low field dc χ(T) data shows an antiferromagnetic – like (AFM) anomaly associated with a Néel temperature T_N = 10.8 K for GdCu_4Au. In the paramagnetic region above T_N, χ(T) data follows the Curies – Weiss law with an effective magnetic moment μ_e_f_f = 7.444(1) μ_B and paramagnetic Weiss temperature θ_P = -15.01(2) K. The experimental value of is close to the calculated value of 7.94 μ_B expected for the free Gd"3"+-ion. The field-cooled (FC) and zero-field-cooled (ZFC) χ(T) data provide evidence for the formation of spin-glass state with a freezing temperature T_f = 15 K. σ(μ_0H) measured in the ordering region (below TN) shows that GdCu_4Au undergoes metamagnetic transition above 0.7 T, characterized by a slight upward curvature above this field. Measurement of σ(μ_0H) in the paramagnetic regions show a linear behaviour up to 0.7 T and a downward curvature at high fields. C_P(T) data shows an AFM – like phase transition at T_N = 10.4 K close to the phase transition observed in χ(T) results. The 4f-electron entropy reaches the value of Rln2 close to T_N at 9.02 K and reaches the value of Rln(2J + 1) at T = 180 K
Source
SCES2014: International conference on strongly correlated electron systems 2014; Grenoble (France); 7-14 Jul 2014; Available from http://dx.doi.org/10.1088/1742-6596/592/1/012050; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Literature Type
Conference
Journal
Journal of Physics. Conference Series (Online); ISSN 1742-6596;
; v. 592(1); [6 p.]

Country of publication
ANTIFERROMAGNETISM, ATOMIC FORCE MICROSCOPY, COPPER COMPOUNDS, CUBIC LATTICES, CURIE-WEISS LAW, ENTROPY, GADOLINIUM COMPOUNDS, GOLD COMPOUNDS, INTERMETALLIC COMPOUNDS, MAGNETIC MOMENTS, MAGNETIC SUSCEPTIBILITY, MAGNETIZATION, NEEL TEMPERATURE, PARAMAGNETISM, POWDERS, SPECIFIC HEAT, SPIN GLASS STATE, TEMPERATURE DEPENDENCE, X-RAY DIFFRACTION
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