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AbstractAbstract
[en] We study the size effect on the confinement of a hydrogen atom in a spherical box of impenetrable walls. We compute the energy of the ground and a few excited states as a function of the box radius R _c. To obtain the energy eigenvalues and eigenfunctions we utilize the linear variational method via a basis set of free-particle-in-a-box wave functions. For small values of R _c convergence is attained with a small number of basis set functions, whereas for R _c ≥ 5.0 au, it is necessary to use over 100 terms in the expansion. (paper)
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Available from http://dx.doi.org/10.1088/0143-0807/37/1/015401; Country of input: International Atomic Energy Agency (IAEA)
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