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AbstractAbstract
[en] This research thesis reports the comparison of, on the one hand, direct measurements of de-swelling resistance of latex dispersions obtained by osmotic pressure with, on the other hand, predictions made by models of electrostatic interactions. This resistance is explained in the case of sulphate-stabilised polystyrene particles (direct repulsion between charged particles), and in the case of copolymer (ps-pba) particles covered by an amphiphilic polymer (interactions between surface macromolecules and polymers). The study of de-swelling and swelling cycles highlights the existence of thresholds beyond which the concentrated dispersion has some cohesion. This irreversibility can be modelled by a Van der Waals attraction. The role of hydrophobic forces in latex destabilisation is studied
[fr]
On compare des mesures directes de la resistance au degonflement de dispersions de latex, obtenues par compression osmotique, avec les predictions de modeles d'interactions electrostatiques. Dans le cas de particules de polystyrene (ps) stabilisees par des groupes sulfate, cette resistance est due a des repulsions directes entre particules chargees. Pour des particules copolymeriques (ps-pba) couvertes par un copolymere amphiphile, elle provient d'interactions entre macromolecules de surface et entre polymeres relargues dans le milieu. Des cycles de degonflement et de regonflement osmotiques mettent en evidence des seuils, au-dela desquels la dispersion concentree a une certaine cohesion. Cette irreversibilite ne peut etre modelisee par une attraction de Van der Waals. Les forces hydrophobes semblent destabiliser le latex ps. Le collage des particules ps-pba est du a un pontage entre les macromolecules de surface. Ainsi, le caractere associatif et amphiphile des copolymeres de surface determine le comportement de telles dispersions lors des experiences de degonflement et regonflement osmotiquesOriginal Title
Degonflement et regonflement osmotiques de dispersions de latex
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Source
6 Oct 1993; 235 p; 69 refs.; Available from the INIS Liaison Officer for France, see the 'INIS contacts' section of the INIS website for current contact and E-mail addresses: http://www.iaea.org/inis/Contacts/; These de Doctorat de l'Universite Paris 6, Specialite: Chimie - Physique
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