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Buss, Wolfram; Graham, Margaret C.; Shepherd, Jessica G.; Mašek, Ondřej, E-mail: ondrej.masek@ed.ac.uk2016
AbstractAbstract
[en] The term “marginal biomass” is used here to describe materials of little or no economic value, e.g. plants grown on contaminated land, food waste or demolition wood. In this study 10 marginal biomass-derived feedstocks were converted into 19 biochars at different highest treatment temperatures (HTT) using a continuous screw-pyrolysis unit. The aim was to investigate suitability of the resulting biochars for land application, judged on the basis of potentially toxic element (PTE) concentration, nutrient content and basic biochar properties (pH, EC, ash, fixed carbon). It was shown that under typical biochar production conditions the percentage content of several PTEs (As, Al, Zn) and nutrients (Ca, Mg) were reduced to some extent, but also that biochar can be contaminated by Cr and Ni during the pyrolysis process due to erosion of stainless steel reactor parts (average + 82.8% Cr, + 226.0% Ni). This can occur to such an extent that the resulting biochar is rendered unsuitable for soil application (maximum addition + 22.5 mg Cr kg"−"1 biochar and + 44.4 mg Ni kg"−"1 biochar). Biomass grown on land heavily contaminated with PTEs yielded biochars with PTE concentrations above recommended threshold values for soil amendments. Cd and Zn were of particular concern, exceeding the lowest threshold values by 31-fold and 7-fold respectively, despite some losses into the gas phase. However, thermal conversion of plants from less severely contaminated soils, demolition wood and food waste anaerobic digestate (AD) into biochar proved to be promising for land application. In particular, food waste AD biochar contained very high nutrient concentrations, making it interesting for use as fertiliser. - Highlights: • Marginal biomass feedstocks are materials of little economic value. • Biochar from biomass grown on PTE-rich soils tends to exceed guideline values. • Biochar from biomass with high mineral content can be a beneficial nutrient source. • Cr and Ni from the steel reactors can contaminate biochar to a significant extent.
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S0048-9697(15)31129-3; Available from http://dx.doi.org/10.1016/j.scitotenv.2015.11.148; Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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ALLOYS, CARBON ADDITIONS, CHEMICAL ANALYSIS, CHEMICAL REACTIONS, COMBUSTION PRODUCTS, DECOMPOSITION, DIMENSIONLESS NUMBERS, ELECTRICAL PROPERTIES, ELEMENTS, ENERGY SOURCES, GRAVIMETRIC ANALYSIS, HIGH ALLOY STEELS, IRON ALLOYS, IRON BASE ALLOYS, MANAGEMENT, METALS, NONMETALS, PHYSICAL PROPERTIES, PYROLYSIS PRODUCTS, QUANTITATIVE CHEMICAL ANALYSIS, RENEWABLE ENERGY SOURCES, RESIDUES, STEELS, THERMAL ANALYSIS, THERMOCHEMICAL PROCESSES, TRANSITION ELEMENT ALLOYS, TRANSITION ELEMENTS, WASTE DISPOSAL, WASTE MANAGEMENT
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