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Zieliński, Mateusz; Dopieralska, Jolanta; Belka, Zdzislaw; Walczak, Aleksandra; Siepak, Marcin; Jakubowicz, Michal, E-mail: mateusz.zielinski@amu.edu.pl, E-mail: dopieralska@amu.edu.pl, E-mail: zbelka@amu.edu.pl, E-mail: awalczak@amu.edu.pl, E-mail: siep@amu.edu.pl, E-mail: mjakub@amu.edu.pl2016
AbstractAbstract
[en] Anthropogenic impact on surface waters and other elements in the environment was investigated in the Noteć River basin in central Poland. The approach was to trace changes in the Sr isotope composition ("8"7Sr/"8"6Sr) and concentration in space and time. Systematic sampling of the river water shows a very wide range of "8"7Sr/"8"6Sr ratios, from 0.7089 to 0.7127. This strong variation, however, is restricted to the upper course of the river, whereas the water in the lower course typically shows "8"7Sr/"8"6Sr values around 0.7104–0.7105. Variations in "8"7Sr/"8"6Sr are associated with a wide range of Sr concentrations, from 0.14 to 1.32 mg/L. We find that strong variations in "8"7Sr/"8"6Sr and Sr concentrations can be accounted for by mixing of two end-members: 1) atmospheric waters charged with Sr from the near-surface weathering and wash-out of Quaternary glaciogenic deposits, and 2) waters introduced into the river from an open pit lignite mine. The first reservoir is characterized by a low Sr content and high "8"7Sr/"8"6Sr ratios, whereas mine waters display opposite characteristics. Anthropogenic pollution is also induced by extensive use of fertilizers which constitute the third source of Sr in the environment. The study has an important implication for future archeological studies in the region. It shows that the present-day Sr isotope signatures of river water, flora and fauna cannot be used unambiguously to determine the “baseline” for bioavailable "8"7Sr/"8"6Sr in the past. - Highlights: • Sr isotopes fingerprint water sources and their interactions in a complex river system. • Mine waters and fertilizers are critical anthropogenic additions in the river water. • Limited usage of environmental isotopic data in archeological studies. • Sr budget of the river is dynamic and temporary.
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S0048-9697(16)30036-5; Available from http://dx.doi.org/10.1016/j.scitotenv.2016.01.036; Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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ALKALINE EARTH ISOTOPES, BETA DECAY RADIOISOTOPES, BROWN COAL, CARBONACEOUS MATERIALS, COAL, DEVELOPING COUNTRIES, DIMENSIONLESS NUMBERS, EASTERN EUROPE, ELECTRON CAPTURE RADIOISOTOPES, ENERGY SOURCES, EUROPE, EVEN-EVEN NUCLEI, EVEN-ODD NUCLEI, FOSSIL FUELS, FUELS, HOURS LIVING RADIOISOTOPES, HYDROGEN COMPOUNDS, INTERMEDIATE MASS NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MATERIALS, NUCLEI, OXYGEN COMPOUNDS, RADIOISOTOPES, STABLE ISOTOPES, STRONTIUM ISOTOPES, SURFACE WATERS
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