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Wang, Qingguo; Zhou, Xue; Zeng, Jinxia; Wang, Jizeng, E-mail: qwang@qust.edu.cn2016
AbstractAbstract
[en] In this paper, the electron beam irradiation technology being more suitable for the industry application is explored to fabricate the acrylic acid (AAc) monomer-grafted polyvinyl alcohol (PVA-g-AAc) hydrogels. ATR-IR spectra of the PVA-g-AAc hydrogels shows an obvious absorption peak of the −C=O group at 1701 cm"−"1, indicating that the AAc monomers were grafted onto the PVA macromolecules. This paper also studied some effects of the mass ratio of PVA/AAc, pH of buffer solution and irradiation dosage on the water swelling properties of the electron beam irradiated PVA-g-AAc hydrogels. The water swelling ratio of PVA-g-AAc hydrogels decreases with increased irradiation dosage and mass ratio of PVA/AAc, whereas swelling ratio increases with increased pH of buffer solution and soaking time. The water-swelling behavior of PVA-g-AAc hydrogels occurred easily in an alkaline environment, particularly in a buffer solution with pH 9.2. Both PVA-g-AAc hydrogels (PVA/AAc = 1/5, w/w) irradiated with 5 kilogray (kGy) and PVA-g-AAc hydrogels (PVA/AAc = 1/1, w/w) irradiated with 15 kGy could easily absorb water and lead to high water swelling ratios (up to about 600%), which are potential candidates to meet the requirements for some biomedical applications.
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S0168-583X(15)01265-3; Available from http://dx.doi.org/10.1016/j.nimb.2015.12.020; Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
Journal
Nuclear Instruments and Methods in Physics Research. Section B, Beam Interactions with Materials and Atoms; ISSN 0168-583X;
; CODEN NIMBEU; v. 368; p. 90-95

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ALCOHOLS, BEAMS, CARBOXYLIC ACIDS, COLLOIDS, DEFORMATION, DISPERSIONS, ELEMENTARY PARTICLES, FERMIONS, GELS, HYDROGEN COMPOUNDS, HYDROXY COMPOUNDS, LEPTON BEAMS, LEPTONS, MONOCARBOXYLIC ACIDS, ORGANIC ACIDS, ORGANIC COMPOUNDS, ORGANIC POLYMERS, OXYGEN COMPOUNDS, PARTICLE BEAMS, POLYMERS, POLYVINYLS, SORPTION, SPECTRA, TRANSPLANTS
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