[en] An electron spectrometry set-up was built at IRMM consisting of a vacuum chamber with a moveable source holder and windowless Peltier-cooled silicon drift detector (SDD). The SDD is well suited for measuring low-energy x rays and electrons emitted from thin radioactive sources with low self-absorption. The attainable energy resolution is better than 0.5 keV for electrons of 30 keV. It has been used to measure the conversion electron spectra of three plutonium isotopes, i.e. "2"3"8Pu, "2"3"9Pu, "2"4"0Pu, as well as "2"4"1Am (being a decay product of "2"4"1Pu). The obtained mixed x-ray and electron spectra are compared with spectra obtained with a close-geometry set-up using another SDD in STUK and spectra measured with a Si(Li) detector at IRMM. The potential of conversion electron spectrometry for isotopic analysis of mixed plutonium samples is investigated. With respect to the "2"4"0Pu/"2"3"9Pu isotopic ratio, the conversion electron peaks of both isotopes are more clearly separated than their largely overlapping peaks in alpha spectra. - Highlights: • Built set-up for conversion electron spectrometry with silicon drift detector. • Conversion electron spectra measured from "2"3"8","2"3"9","2"4"0Pu and "2"4"1Am. • Compared with other SDD set-up and Si(Li) detector.