[en] Highlights: • Co doped ZnO films have been deposited on Si (100) substrates via Pulsed electron beam ablation. • The effects of deposition temperature and accelerating voltage on the films have been assessed and discussed. • Films consist of Co-rich globular nanoparticulates (∼20 nm–300 nm) having roughness ∼3 nm–23 nm. • XPS and XRD analyses confirm the presence of metallic Co in the films. • The findings hint at the potential of the deposited films as model nano-catalysts in a variety of chemical processes. - Abstract: Cobalt-doped ZnO (CZO) thin films have been deposited from Co_xZn_1-xO (x = 0.20) target on Si (100) substrate by pulsed electron beam ablation (PEBA). The effects of process temperature (350 °C–800 °C) and electron beam acceleration voltage (15 kV, 16 kV) on the deposited films have been assessed. The films have been prepared at constant beam pulse frequency (2 Hz) and Argon background pressure (∼3 mTorr). The structure and surface morphology of CZO films have been investigated by scanning electron microscopy (SEM) and atomic force microscopy (AFM). As per SEM data, the results show that the films consist of Co rich nano-sized globules (∼20 nm–300 nm). Energy dispersive x-ray (EDX) measurements reveal that Co content in the films seems to be unaffected by accelerating voltage while it increases with temperature in the range 350 °C–450 °C. At higher deposition temperatures (600 °C & 800 °C), the films exhibit faceted particles and are relatively rough. The films deposited at 800 °C consist of a predominantly Co phase. X-ray photoelectron spectroscopy (XPS) data confirm the presence of metallic cobalt in the films, whose content increases with temperature but is practically unaffected by beam voltage. X-ray diffraction (XRD) analysis confirms the presence of herxagonal close-packed (hcp) metallic cobalt in the films.