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AbstractAbstract
[en] Y2O2S:Eu3+ thin films were deposited on Si (100) substrate using pulsed laser deposition technique (PLD) under 20 mTorr oxygen pressure. The effects of deposition time on the structural and photoluminescence properties were studied. X-ray diffraction analysis shows the formation of cubic and hexagonal crystal structures depending on the growth duration. Thin films deposited for 15, 30, 45 and 60 min have cubic phase with impurities of Y2O3, while that grown for 90 min is hexagonal phase. The crystallite size for the cubic phase was observed to increase from 58.4 to 79.2 nm with increase in deposition time. Scanning electron micrographs show the surface morphology comprising spherical particles distributed randomly over the surface with film prepared for longer duration having much larger grain size. Energy-dispersive X-ray spectrum confirms the presence of all the main elements of the Y2O2S:Eu3+ phosphor. Photoluminescence measurements showed blue emission of the films with the most intense peak observed at 452 nm, which is due to the Y2O2S host emission. The band gap values for the cubic phase calculated from absorbance spectra using the Tauc's relation decreased from 4.35 to 4.18 eV with increase in deposition time attributed to change in crystallites size. (orig.)
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Source
Available from: http://dx.doi.org/10.1007/s00339-018-1768-1
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Journal Article
Journal
Applied Physics. A, Materials Science and Processing; ISSN 0947-8396;
; CODEN APAMFC; v. 124(5); p. 1-9

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ABSORPTION SPECTRA, CUBIC LATTICES, DEPOSITION, DOPED MATERIALS, EMISSION SPECTRA, ENERGY GAP, ENERGY SPECTRA, EUROPIUM ADDITIONS, HEXAGONAL LATTICES, IMPURITIES, LASER RADIATION, PARTICLE SIZE, PHOTOLUMINESCENCE, PULSED IRRADIATION, SCANNING ELECTRON MICROSCOPY, THIN FILMS, VISIBLE SPECTRA, X-RAY DIFFRACTION, X-RAY SPECTRA, YTTRIUM OXIDES
ALLOYS, CHALCOGENIDES, COHERENT SCATTERING, CRYSTAL LATTICES, CRYSTAL STRUCTURE, DIFFRACTION, ELECTROMAGNETIC RADIATION, ELECTRON MICROSCOPY, EMISSION, EUROPIUM ALLOYS, FILMS, IRRADIATION, LUMINESCENCE, MATERIALS, MICROSCOPY, OXIDES, OXYGEN COMPOUNDS, PHOTON EMISSION, RADIATIONS, RARE EARTH ADDITIONS, RARE EARTH ALLOYS, SCATTERING, SIZE, SPECTRA, THREE-DIMENSIONAL LATTICES, TRANSITION ELEMENT COMPOUNDS, YTTRIUM COMPOUNDS
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