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[en] This presentation concerns the electrochemical behavior of plutonium in HNO3 medium as well as in TBP. The two redox couples Pu(IV)/Pu(III) and Pu(VI)/Pu(V) will be described more from a thermodynamic point of view. The redox mechanism of the Pu(IV)/Pu(III) pair in a nitric medium will also be discussed following the use of the coupling of electrochemical and spectroscopic techniques.
Source
Czech Chemical Society, Prague (Czech Republic); 224 p; 2018; p. 100; 18. radiochemical conference; Marianske Lazne (Czech Republic); 13-18 May 2018; ISSN 2336-7202; 
; Available on-line: https://indico.fjfi.cvut.cz/event/82/attachments/701/913/Booklet_of_Abstracts_CCSSS_162_2018_49_268.pdf; Presented in section 'Chemistry of actinide and trans-actinide elements' as contribution TAN.L11 (Id: 655)
; Available on-line: https://indico.fjfi.cvut.cz/event/82/attachments/701/913/Booklet_of_Abstracts_CCSSS_162_2018_49_268.pdf; Presented in section 'Chemistry of actinide and trans-actinide elements' as contribution TAN.L11 (Id: 655)