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[en] This presentation concerns the electrochemical behavior of plutonium in HNO3 medium as well as in TBP. The two redox couples Pu(IV)/Pu(III) and Pu(VI)/Pu(V) will be described more from a thermodynamic point of view. The redox mechanism of the Pu(IV)/Pu(III) pair in a nitric medium will also be discussed following the use of the coupling of electrochemical and spectroscopic techniques.