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Honma, Kenichi; Yoshikawa, Tomohisa; Kataoka, Makoto; Tamashige, Takamiki; Kobayashi, Wataru; Takahashi, Yuuji; Hisaoka, Natsuki, E-mail: kenichi_honma@taiheiyo-cement.co.jp2019
AbstractAbstract
[en] This study is an entrusted verification research project for Cs removal, volume reduction and recycling technology for radioactive waste. The purpose is to recycle radioactive waste, including soil removed in Iitate Village and incineration ash generated in an incinerator, into safe construction material products at a pilot plant built next to the incinerator. A preliminary electric furnace test was carried out using various types of radioactive waste including removed soil, fluidized bed combustion fly ash, stoker bottom ash and stoker fly ash. It was found that, with any of the waste types tested, residual radioactive Cs (r-Cs) concentration could be reduced to below the clearance level of 100 Bq/kg by controlling CaO/SiO2 to over 2.0 in weight and Cl/K to 0.8 to 1.1 in moles and heat treating the raw material at 1300degC or above. In the verification test using the pilot plant, the raw materials using fluidized bed combustion fly ash, stoker bottom ash or removed soil achieved a yield rate of accepted product of over 95%, with residual r-Cs concentration after the heat treatment successfully reduced to below 100 Bq/kg by controlling CaO/SiO2 of the raw materials and optimizing the heat treatment operation to minimize adhesion of molten raw materials to the kiln inner wall. Vaporized r-Cs was recovered by a bag filter and stored as byproduct. The r-Cs in the byproduct was found condensed to a concentration of 7 to 16 times higher than that in the radioactive waste materials, while the volume of the radioactive waste materials was reduced by 90.6% on average. It was also demonstrated that the r-Cs concentration of exhaust gas was below the detection limit. (author)
[ja]
環境省委託事業として飯舘村蕨平地区において飯舘村内の除去土壌および、隣接する焼却炉で発生する廃却灰を熱処理し、土工資材として再生利用できるレベルまで放射性Csを除去させる技術の実証試験を実施した。事前に電気炉にて検討した結果、除去土壌、流動床飛灰、ストーカ主灰・飛灰いずれにおいても原料のCaO/SiO2比(重量比)を2.0以上、Cl/K比(モル比)を0.8~1.1として、1300°C以上で熱処理することで、生成物中の放射性Cs濃度をクリアランスレベルである100Bq/Kg以下にできることを確認した。仮設資材化炉を用いた試験においても、除去土壌、ストーカ主灰、流動床飛灰いずれの場合にも、C/Sを調整することにより生成物の95%以上を安定して100Bq/kg以下にできることを実証した。放射性Cs汚染物の90.6%が減量されること、最終排ガスからの放射性Cs濃度が検出限界値以下となることも実証した。(著者)Original Title
飯舘村蕨平における放射性物質の分離による焼却灰及び汚染土壌の資材化に関する研究
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Secondary Subject
Source
22 refs., 12 figs., 10 tabs.; 雑誌名:環境放射能除染学会誌
Record Type
Journal Article
Journal
Kankyo Hoshano Josen Gakkai-Shi; ISSN 2187-8382;
; v. 7(4); p. 227-239

Country of publication
ACCIDENTS, AEROSOL WASTES, ASHES, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, BEYOND-DESIGN-BASIS ACCIDENTS, CESIUM ISOTOPES, CHEMICAL REACTIONS, COMBUSTION, COMBUSTION PRODUCTS, ELECTRON CAPTURE RADIOISOTOPES, HOURS LIVING RADIOISOTOPES, INTERMEDIATE MASS NUCLEI, INTERNAL CONVERSION RADIOISOTOPES, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, MANAGEMENT, MATERIALS, NUCLEI, ODD-EVEN NUCLEI, ODD-ODD NUCLEI, OXIDATION, RADIOACTIVE MATERIALS, RADIOACTIVE WASTE MANAGEMENT, RADIOISOTOPES, REACTOR SITES, RESIDUES, STORAGE, THERMOCHEMICAL PROCESSES, WASTE MANAGEMENT, WASTE STORAGE, WASTES, YEARS LIVING RADIOISOTOPES
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