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Yang, Wanli; Devereaux, Thomas P.; Stanford University, CA
SLAC National Accelerator Laboratory, Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Funding organisation: USDOE Office of Science - SC, Basic Energy Sciences (BES) (SC-22) (United States)2018
SLAC National Accelerator Laboratory, Menlo Park, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Funding organisation: USDOE Office of Science - SC, Basic Energy Sciences (BES) (SC-22) (United States)2018
AbstractAbstract
[en] Recent advances in battery science and technology have triggered both the challenges and opportunities on studying the materials and interfaces in batteries. In this paper, we review the recent demonstrations of soft X-ray spectroscopy for studying the interfaces and electrode materials. The focus of this review is on the recently developed mapping of resonant inelastic X-ray scattering (mRIXS) as a powerful probe of battery chemistry with superior sensitivity. Six different channels of soft X-ray absorption spectroscopy (sXAS) are introduced for different experimental purposes. Although conventional sXAS channels remain effective tools for quantitative analysis of the transition-metal states and surface chemistry, we elaborate the limitations of sXAS in both cationic and anionic redox studies. Particularly, based on experimental findings in various electrodes, we show that sXAS is unreliable for studying oxygen redox. We then demonstrate the mRIXS as a reliable technique for fingerprinting oxygen redox and summarize several crucial observations. We conclude that mRIXS is the tool-of-choice to study both the practical issue on reversibility of oxygen redox and the fundamental nature of bulk oxygen states. Finally, we hope this review clarifies the popular misunderstanding on oxygen sXAS results of oxide electrodes, and establishes a reliable technique for detecting oxygen redox through mRIXS.
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OSTIID--1464126; AC02-76SF00515; AC02-05CH11231; Available from https://www.osti.gov/servlets/purl/1464126; DOE Accepted Manuscript full text, or the publishers Best Available Version will be available free of charge after the embargo period; arXiv:1804.04564; Country of input: United States
Record Type
Journal Article
Journal
Journal of Power Sources; ISSN 0378-7753;
; v. 389; p. 188-197

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