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Jia, Zheng; Choi, Junseo; Park, Sunggook, E-mail: sunggook@lsu.edu2018
AbstractAbstract
[en] Nanoimprint molds made of soft polymeric materials have advantages of low demolding force and low fabrication cost over Si or metal-based hard molds. However, such advantages are often sacrificed by their reduced replication fidelity associated with the low mechanical strength. In this paper, we studied replication fidelity of different UV-resin molds copied from a Si master mold via UV nanoimprint lithography (NIL) and their thermal imprinting performance into a thermoplastic polymer. Four different UV-resins were studied: two were high surface energy UV-resins based on tripropyleneglycol diacrylate (TPGDA resin) and polypropyleneglycol diacrylate (PPGDA resin), and the other two were commercially available, low surface energy poly-urethane acrylate (PUA resin) and fluorine-containing (MD 700) UV-resins. The replication fidelity among the four UV-resins during UV nanoimprint lithograph from a Si master with sharp nanostructures was in the increasing order of (poorest) PUA resin < MD 700 < PPGDA resin < TPGDA resin (best). The results show that the high surface energy and small monomer size are keys to achieving good UV-resin filling into sharp nanostructures over the viscosity of the resin solution. When the four UV-resin molds were used for thermal-NIL into a thermoplastic polymer, the replication fidelity was in the increasing order of (poorest) MD 700 < TPGDA resin < PUA resin (best), which follows the same order of their Young’s moduli. Our results indicate that the selection of an appropriate UV-resin for NIL molds requires consideration of the replication fidelities in the mold fabrication and the subsequent thermal-NIL into thermoplastic polymers. (paper)
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Source
Available from http://dx.doi.org/10.1088/1361-6528/aacd33; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Nanotechnology (Print); ISSN 0957-4484;
; v. 29(36); [8 p.]

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CARBOXYLIC ACID SALTS, ELECTROMAGNETIC RADIATION, ELEMENTS, ENERGY, FREE ENERGY, GEOLOGY, HALOGENS, MATERIALS, NONMETALS, ORGANIC COMPOUNDS, ORGANIC POLYMERS, PETROCHEMICALS, PETROLEUM PRODUCTS, PETROLOGY, PHYSICAL PROPERTIES, PLASTICS, POLYAMIDES, POLYMERS, RADIATIONS, SURFACE PROPERTIES, SYNTHETIC MATERIALS, THERMODYNAMIC PROPERTIES
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