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AbstractAbstract
[en] Hydrophilic 2,6-bis[1-(propan-1-ol)-1,2,3-triazol-4-yl)] pyridine (PyTri-Diol) was synthesized and tested for selective complexation of Am(III) into nitric acid solution from acidic bis(2-ethylhexyl)phosphoric (HDEHP) acid extractant. As the result of stripping experiments showed, PyTri-Diol dramatically promote Am(III) stripping in nitric acid up to 0.5 mol/L while the majority of Eu(III) was hold in the HDEHP phase. Separation factors in the range of 900 are achieved and PyTri-Diol remains active in nitric acid up to 0.5 mol/L without buffered solution or salting-out agent. The above properties of PyTri-Diol demonstrate the great potential for separating the minor actinides from the lanthanides in the TALSPEAK process. (author)
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34 refs.
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Journal Article
Journal
Journal of Radioanalytical and Nuclear Chemistry; ISSN 0236-5731;
; CODEN JRNCDM; v. 323(1); p. 283-289

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ACTINIDE COMPOUNDS, ALCOHOLS, AZINES, DIRECT REACTIONS, ELEMENTS, ESTERS, HETEROCYCLIC COMPOUNDS, HYDROGEN COMPOUNDS, HYDROXY COMPOUNDS, INORGANIC ACIDS, INORGANIC COMPOUNDS, METALS, NITROGEN COMPOUNDS, NUCLEAR REACTIONS, ORGANIC COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, ORGANIC PHOSPHORUS COMPOUNDS, OXYGEN COMPOUNDS, PHOSPHORIC ACID ESTERS, PYRIDINES, TRANSFER REACTIONS, TRANSPLUTONIUM COMPOUNDS, TRANSURANIUM COMPOUNDS
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