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AbstractAbstract
[en] This paper presents the results of an investigation into the distribution of rare earth elements (REEs) in diatomite and tridymite from the Kozhuf Mountain volcanic area. The REEs comprise fifteen chemical elements from lanthanum to lutetium (atomic numbers 57-71), characterized by similar chemical properties. In order to study their distribution, samples of the Vitachevo diatomite and Alshar tridymite sediments were taken and analyzed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). The chondritic normalization curves show enrichment in light rare earth elements (LREEs), a negative europium (Eu) anomaly in all samples, and a progressive depletion of heavy rare earth elements (HREEs). Two hypotheses are discussed: the nature of the parent rocks of the sediments (volcanic rocks of the Kozhuf Mountain) and the physico-chemical conditions of sedimentation, particularly complexation and oxido-reduction phenomena. There is a strong correlation between the distribution of REEs in volcanic rocks and the distribution of REEs in sedimentary diatomite and the acidic volcanics (tridymite). (author)
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Available from the National and University Library ' Kliment Ohridski' , Skopje (MK), also availabale online from http://js.ugd.edu.mk/index.php/GEOLMAC/article/view/3025/2730; 45 refs., 6 tab., 13 figs.; UDC: 552.581.08:551.21(497.714/.715:234.42); The edition was published in June 2019
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