[en] A highly diastereoselective synthesis of sulfur containing C₂-symmetric chiral pincer ligands, has been achieved. Additionally, we have succeeded in a syntheses of new sulfur containing C₂-symmetric chiral pincer compounds such as organopalladium and organorhodium. The control of the ligating properties of metal centers of metal catalyst with a well defined ligand system is one of the important goals of organic chemistry. Chiral pincer complexes consist of an enantiopure tridentate skeleton bound to a metal by at least one metal-carbon σ bond. The highly protected environment for the resident metal gives pincer complexes with excellent potential as catalysts in a wide variety of asymmetric organic reactions, even though the degree of asymmetric induction has not been great so far, which would warrant further endeavor in designing and synthesizing new pincer compounds