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He, Haiyong; Fu, Wei; Wang, Hongtao; Wang, Hong; Jin, Chuanhong; Fan, Hong Jin; Liu, Zheng, E-mail: fanhj@ntu.edu.sg, E-mail: z.liu@ntu.edu.sg2017
AbstractAbstract
[en] Highlights: • An interfacial engineering method is used to obtain self-stainable silica modified SnO2/G nanosheet. • Tin elements can diffuse into silica and along G to finally plate on G during cycling. • Aggregation of LiSn alloy was effectively avoided. • High specific capacities (>1950 mA h/g at a current density of 500 mA/g) can be maintained up to 1000 cycles without clear fading. Tin oxide is an attractive anode material for lithium battery, on the grounds of its high capacity (above 2000 mAh/g), environmental friendliness and low cost. However, the large volumetric expansion (>200%) and aggregation of lithium-tin alloy cause significant capacity fading after only a few hundred cycles. In this work, we design a new type of SnO2 based composite electrode to address the above two issues. SnO2 nanoparticles uniform anchored on graphene are covered by a thin layer of silica. Upon cycling, tin can diffuse into the coating layer and also spread laterally on the graphene surface to form a continuous thin film of Li2SnxSiO3+y. Such design diminishes the volumetric expansion of individual Sn particles and aggregation of lithium-tin alloy, but also dramatically decreases the lithium transport distance and diffusion barrier. Additionally, we propose that diffusion-induced defects on surface offer capacitive-like regions to absorb extra lithium ions. As a result, this unique structure can maintain a high capacity of 1950 mAh/g after 1000 cycles at a specific current of 500 mA/g with negligible capacity loss, and excellent reversibility with a columbic efficiency retention over 99%.
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S2211285517301489; Available from http://dx.doi.org/10.1016/j.nanoen.2017.03.017; Copyright (c) 2017 Elsevier Ltd. All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
Journal
Nano Energy (Print); ISSN 2211-2855;
; v. 34; p. 449-455

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