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Wu, Wu-Qiang; Chen, Dehong; Li, Feng; Pascoe, Alexander R.; Cheng, Yi-Bing; Caruso, Rachel A., E-mail: dehongc@unimelb.edu.au, E-mail: yibing.cheng@monash.edu, E-mail: rcaruso@unimelb.edu.au2017
AbstractAbstract
[en] Highlights: • Electron-rich TiO2 films are prepared via a glucose-assisted solvothermal process. • Bilayer dense/porous CH3NH3PbI3 films are formed. • Efficient light harvesting and charge collection within devices realized. • Integrated planar/bulk heterojunction solar cell attains an efficiency of 17.75%. To achieve high-performing perovskite solar cells (PSCs) interfacial engineering of the perovskite thin film and charge carrier-selective layers is vital for fast extraction of photogenerated electrons and holes, and the suppression of electron-hole recombination. Herein, a glucose-assisted self-assembly solvothermal protocol is reported to prepare electron-rich TiO2 thin films as effective electron transport layers exhibiting enhanced electron mobility. Bilayer structured CH3NH3PbI3 perovskite films are spontaneously formed, consisting of a flat and dense bottom layer forming the TiO2/CH3NH3PbI3 planar heterojunction and a textured and porous top layer elongating in the vertical direction forming the CH3NH3PbI3/spiroMeOTAD bulk heterojunction. The integrated planar and bulk dual heterojunction based PSCs are efficient in light harvesting and charge collection, and thus yield power conversion efficiencies up to 17.75% and a stabilized power output above 17.20%. Integrating both planar and bulk heterojunctions into a PSC assembly provides an effective approach for fabricating highly efficient perovskite optoelectronic devices.
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S2211285516305936; Available from http://dx.doi.org/10.1016/j.nanoen.2016.12.029; Copyright (c) 2016 Elsevier Ltd. All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Nano Energy (Print); ISSN 2211-2855;
; v. 32; p. 187-194

Country of publication
CHALCOGENIDES, COUPLING, DIRECT ENERGY CONVERTERS, ELECTRONIC EQUIPMENT, EQUIPMENT, FILMS, MATERIALS, MINERALS, MOBILITY, OPTICAL EQUIPMENT, OXIDE MINERALS, OXIDES, OXYGEN COMPOUNDS, PARTICLE MOBILITY, PEROVSKITES, PHOTOELECTRIC CELLS, PHOTOELECTRIC EFFECT, PHOTOVOLTAIC CELLS, SEMICONDUCTOR JUNCTIONS, SEPARATION PROCESSES, SOLAR EQUIPMENT, TITANIUM COMPOUNDS, TRANSDUCERS, TRANSITION ELEMENT COMPOUNDS
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