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Yang, Zhengrui; Xie, Jiangsheng; Arivazhagan, V.; Xiao, Ke; Qiang, Yaping; Huang, Kun; Hu, Ming; Cui, Can; Yu, Xuegong; Yang, Deren, E-mail: yuxuegong@zju.edu.cn, E-mail: mseyang@zju.edu.cn2017
AbstractAbstract
[en] Highlights: • We demonstrate for the first time the utilization of GQDs as an additive to PCBM. • The device maintains ~80% of its PCE under continuous 300 h full spectrum sunlight. • GQDs: PCBM resulted in a high efficient (17.56%) PSC with negligible hysteresis. • All component layers are deposited at room temperature and treated below 100 °C. Organic-inorganic hybrid perovskite solar cells (PSCs) have triggered a great deal of research on organic electron transport layers, such as phenyl C61 butyric acid methyl ester (PCBM), due to their potential application as a strong contender in photovoltaic industry with simple fabrication process and low cost. However, the low electrical conductivity and electron mobility of PCBM hinder the promotion of PSCs. Here we report a successful case of graphene quantum dots (GQDs) doping into PCBM electron transport layer (ETL) of planar N-I-P PSCs, resulting in an obvious increase in PCBM conductivity together with the enhanced charge extraction and reduced the trap state density of perovskite films. A low doping ratio (0.5 wt%) would be efficient to boost the Voc, Jsc and FF, a PCE of 17.56% is achieved. More importantly, the light stability of PSCs with PCBM: GQDs was improved: the unpackaged cells can keep > 80% of the initial PCE under simulated sunlight with the full UV component present after 300 h, in contrast to the reference device that dropped < 50% during the same period of time.
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S2211285517304779; Available from http://dx.doi.org/10.1016/j.nanoen.2017.08.008; Copyright (c) 2017 Published by Elsevier Ltd.; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
Journal
Nano Energy (Print); ISSN 2211-2855;
; v. 40; p. 345-351

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CARBON, CARBOXYLIC ACIDS, DIRECT ENERGY CONVERTERS, ELECTROMAGNETIC RADIATION, ELEMENTS, EQUIPMENT, MATERIALS, MINERALS, MOBILITY, MONOCARBOXYLIC ACIDS, NANOSTRUCTURES, NONMETALS, ORGANIC ACIDS, ORGANIC COMPOUNDS, OXIDE MINERALS, PARTICLE MOBILITY, PEROVSKITES, PHOTOELECTRIC CELLS, PHOTOELECTRIC EFFECT, PHOTOVOLTAIC CELLS, RADIATIONS, SOLAR EQUIPMENT
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