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König, Stephan; Wolfram, Markus; Bandelow, Steffi; Marx, Gerrit; Schweikhard, Lutz, E-mail: stephan.koenig@physik.uni-greifswald.de2018
AbstractAbstract
[en] Size-selected monoanionic tin clusters Snn−, n = 7 − 75, are stored simultaneously with electrons in a Penning trap to produce poly-anionic clusters by electron attachment. In addition to doubly and triply charged clusters with the size of the precursors, fragments such as Sn−n−7, Sn−n−10 or Snn−15 are observed in the lower size range (n ≲ 50). The latter come along with the clusters Sn−10 and Sn−15, probably due to fission of doubly charged clusters as in the case of the group-14 neighbor-element lead [König et al., Phys. Rev. Lett. 120, 163001 (2018)]. Furthermore, prominent doubly charged products Sn2−n−15 seem to be produced by break-off of neutral decamers, a feature not yet observed for any other dianionic cluster. In addition, while almost no monomer evaporation is observed for singly charged clusters, this process does occur for doubly charged ones. Graphical abstract: .
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Copyright (c) 2018 EDP Sciences, SIF, Springer-Verlag GmbH Germany, part of Springer Nature; This record replaces 50015997; This record replaces 50034352; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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European Physical Journal. D, Atomic, Molecular and Optical Physics; ISSN 1434-6060;
; v. 72(9); p. 1-7

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