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Weisenburger, A.; Müller, G., E-mail: Alfons.weisenburger@kit.edu
Challenges for Coolants in Fast Neutron Spectrum Systems2020
Challenges for Coolants in Fast Neutron Spectrum Systems2020
AbstractAbstract
[en] Liquid Pb and PbBi are among the promising coolants for reactors operating in fast neutron spectrum. Beside its excellent neutronic properties, Pb and PbBi offer improved safety features. But, deficient compatibility of structural materials with the liquid metals especially at higher temperatures is a major challenge to be solved for the use of Pb and PbBi cooled fast nuclear systems like MYRRHA, BREST and others at time under consideration. The major driving force for corrosion attack is the solubility of steel alloying elements like Ni, Fe and Cr in the HLM. Addition of oxygen to the HLM to provide in-situ formation of protective oxide scales is the mitigation mechanism of choice but limits the operating temperature window. Ferritic steels are not considered at present due to their susceptibility to liquid metal embrittlement. The use of austenitic steels of 316type is limited to temperatures below 450°C due to corrosion attack. Even at this temperature localized corrosion was observed at oxygen concentrations in the HLM of about 10-7 wt%. Beside composition and crystal structure, imperfections like twin boundary seems to impact the compatibility of the steel in HLM. To enlarge the operation window of HLM cooled nuclear reactors advanced mitigation measures are under investigation since several years. Alumina forming surface alloyed layers and bulk materials are one option to increase the operating temperature window to 600°C by increasing the corrosion resistant in oxygen containing liquid metals. Fully corrosion resistant coatings like alumina, TiN or W are additional possible options, but require the integrity of the coating at all operating conditions, which is less stringent for the protection methods that rely on inoperation forming capabilities. (author)
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International Atomic Energy Agency, Physics Section, Vienna (Austria); 272 p; ISBN 978-92-0-107820-9;
; ISSN 1011-4289;
; May 2020; p. 176-180; 1. IAEA workshop on challenges for coolants in fast neutron spectrum systems: Chemistry and materials; Vienna (Austria); 5-7 Jul 2017; Consultancy meeting on challenges for coolants in fast neutron spectrum systems: Chemistry and materials; Vienna (Austria); 2-4 Jul 2018; Also available on-line: https://www-pub.iaea.org/MTCD/Publications/PDF/TE-1912_web.pdf; Enquiries should be addressed to IAEA, Marketing and Sales Unit, Publishing Section, E-mail: sales.publications@iaea.org; Web site: http://www.iaea.org/books; 16 refs., 6 figs.; This record replaces 51069852


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ALUMINIUM OXIDES, BREST-OD-300 REACTOR, CHROMIUM, COATINGS, CORROSION PROTECTION, CORROSION RESISTANCE, CRYSTAL STRUCTURE, EMBRITTLEMENT, FAST NEUTRONS, FERRITIC STEELS, IRON, LEAD-BISMUTH EUTECTIC, MYRRHA FACILITY, NEUTRON SPECTRA, NICKEL, OXYGEN, SAFETY, STAINLESS STEEL-316, TITANIUM NITRIDES, TUNGSTEN
ACCELERATOR-DRIVEN SUBCRITICAL SYSTEMS, ALLOYS, ALUMINIUM COMPOUNDS, AUSTENITIC STEELS, BARYONS, BISMUTH ALLOYS, BISMUTH BASE ALLOYS, CARBON ADDITIONS, CHALCOGENIDES, CHROMIUM ALLOYS, CHROMIUM STEELS, CHROMIUM-MOLYBDENUM STEELS, CHROMIUM-NICKEL STEELS, CHROMIUM-NICKEL-MOLYBDENUM STEELS, CORROSION RESISTANT ALLOYS, ELEMENTARY PARTICLES, ELEMENTS, EPITHERMAL REACTORS, EXPERIMENTAL REACTORS, FAST REACTORS, FERMIONS, HADRONS, HEAT RESISTANT MATERIALS, HEAT RESISTING ALLOYS, HIGH ALLOY STEELS, IRON ALLOYS, IRON BASE ALLOYS, LEAD ALLOYS, LEAD COOLED REACTORS, LEAD-BISMUTH COOLED REACTORS, LIQUID METAL COOLED REACTORS, MATERIALS, METALS, MOLYBDENUM ALLOYS, NEUTRONS, NICKEL ALLOYS, NITRIDES, NITROGEN COMPOUNDS, NONMETALS, NUCLEONS, OXIDES, OXYGEN COMPOUNDS, PNICTIDES, POWER REACTORS, REACTORS, REFRACTORY METALS, RESEARCH AND TEST REACTORS, RESEARCH REACTORS, SPECTRA, STAINLESS STEELS, STEEL-CR17NI12MO3, STEELS, SUBCRITICAL ASSEMBLIES, TITANIUM COMPOUNDS, TRANSITION ELEMENT ALLOYS, TRANSITION ELEMENT COMPOUNDS, TRANSITION ELEMENTS
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