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AbstractAbstract
[en] Four solvent complexes of beryllium iodide were prepared by dissolving BeI in N,N-dimethyl formamide (DMF), pyridine (Pyr), N-methyl pyrrolidone (NMP) and 2,6-dimethyl pyridine (2,6-lutidine, Lut). Their crystal structures were established from single crystal X-ray diffraction. For [Be(DMF)]I a new modification is reported (monoclinic, space group P2/c, a = 12.491(2), b = 11.593(2), c = 15.310(3) Å, β = 94.7073(6)°). In [Be(Pyr)]I (monoclinic, space group C2/c, a = 17.8799(13), b = 7.6174(5), c = 18.2611(14) Å, β = 113.508(4)°) and [Be(NMP)]I (orthorhombic, space group Pbca, a = 13.941(5), b = 15.754(3), c = 24.634(7) Å) homoleptic tetrahedral complex cations are formed, while the sterically demanding solvent ligand Lut yields a neutral complex with covalently bound iodine ligands [BeI(Lut)] (monoclinic, space group P2/c, a = 7.8492(9), b = 24.265(3), c = 27.037(3) Å, β = 97.076(3)°). Their electrochemical stability with respect to their application as beryllium electrolytes for deposition of beryllium from solution is discussed.
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Source
Available from: http://dx.doi.org/10.1515/znb-2020-0035; Topical issue on the chemistry of beryllium
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Journal Article
Journal
Zeitschrift fuer Naturforschung. B: Chemical Sciences; ISSN 0932-0776;
; CODEN ZNBSEN; v. 75(5); p. 509-516

Country of publication
ALKALINE EARTH METAL COMPLEXES, ALKALINE EARTH METAL COMPOUNDS, AMIDES, AZINES, AZOLES, BERYLLIUM COMPOUNDS, BERYLLIUM HALIDES, CHEMISTRY, COHERENT SCATTERING, COMPLEXES, CRYSTAL LATTICES, CRYSTAL STRUCTURE, CRYSTALS, DIFFRACTION, HALIDES, HALOGEN COMPOUNDS, HETEROCYCLIC COMPOUNDS, IODIDES, IODINE COMPOUNDS, LACTAMS, ORGANIC COMPOUNDS, ORGANIC NITROGEN COMPOUNDS, PYRIDINES, PYRROLES, SCATTERING, SYMMETRY GROUPS, THREE-DIMENSIONAL LATTICES
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