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Miller, Jamie; Hanson, Bruce; Muller, Frans
WM Symposia, Inc., PO Box 27646, 85285-7646 Tempe, AZ (United States)2019
WM Symposia, Inc., PO Box 27646, 85285-7646 Tempe, AZ (United States)2019
AbstractAbstract
[en] Aims: Convert an Agitated Tube Reactor (ATR) into a counter-current solvent extraction device. Assess effect of liquid fill level on liquid dispersion. The agitated tube reactor (ATR) is an array of connected tubes. The ATR laterally shakes in a sinusoidal path, moving the agitator bar to create mixing. Originally designed by AM Technology as a cocurrent reactor, the ATR has many features that are potentially useful in the nuclear industry: Tubes are connected by non-moving seals; Reduction in seal damage and reduced risk of expensive repairs in radioactive environments; Minimal axial dispersion within a tube; Plug flow; Narrower residence time distributions that traditional technology; Multiple tubes allow for multiple reactions in series; Converting to a counter-current design allows the ATR to be used for solvent extraction; Reprocessing or decommissioning. A 180 ml PERSPEX ATR tube with no liquid flow through was constructed and filled with a 1:1 solvent:aqueous ratio of kerosene and water. The tube was filled such that the total liquid filled 25 %, 50 %, 75 % or 100 % of the tube. A Photron Fastcam SA5, positioned at the side and the end of the tube was set to a frame rate of 5400 fps with a resolution of 1024 x 1024 and 6000 fps with a resolution of 1024 x 896 respectively. Droplets were recorded after 2 minutes of shaking to ensure good mixing. Droplet sizes are used to determine optimum fill level in the ATR. The shaking frequency follows a sinusoidal path and was set to 5 Hz. The images shown in the results section were taken at the peak of the sinusoidal motion. To convert to a counter-current design the two liquids need to be separated at the end of each tube. Liquids have been allowed to separate under gravity separation. Inclusion of baffles to reduce remixing by sloshing. Wall with height corresponding to 25 % fill volume allows kerosene to overflow into separate outlet. Increase in liquid fill level decreases the dispersion of the two liquid phases. Higher dispersion of droplets decreases surface area and therefore increases mass transfer in solvent extraction. 25 % should provide the greatest mass transfer though more work needs to completed to confirm this
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2019; 1 p; WM2019: 45. Annual Waste Management Conference; Phoenix, AZ (United States); 3-7 Mar 2019; Available from: WM Symposia, Inc., PO Box 27646, 85285-7646 Tempe, AZ (US); Country of input: France; 1 ref.; available online at: https://www.xcdsystem.com/wmsym/2019/index.html
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Miscellaneous
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Conference
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DISTILLATES, ENERGY SOURCES, ESTERS, EXTRACTION, FLUID FLOW, FOSSIL FUELS, FUELS, FUNCTIONS, GAS OILS, INDUSTRY, LIQUID FUELS, MATERIALS, NUCLEAR FUELS, ORGANIC COMPOUNDS, ORGANIC POLYMERS, PARTICLES, PETROCHEMICALS, PETROLEUM, PETROLEUM DISTILLATES, PETROLEUM FRACTIONS, PETROLEUM PRODUCTS, PLASTICS, POLYACRYLATES, POLYMERS, POLYVINYLS, REACTOR MATERIALS, SEPARATION PROCESSES, SYNTHETIC MATERIALS
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