Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.019 seconds
AbstractAbstract
[en] Here we present synchrotron-based x-ray diffraction experiments combined with diamond anvil cell and laser heating techniques on the intermetallic rare earth compound TbPt (Pnma and Z = 4) up to 32.5 GPa and ∼1800 K. The lattice parameters of TbPt exhibit continuous compression behavior up to 18.2 GPa without any evidence of phase transformation. Pressure–volume data were fitted to a third-order Birch–Murnaghan equation of state with V 0 = 175.5(2) Å3, = 110(5) GPa and = 3.8(7). TbPt exhibits anisotropic compression with β a > β b > β c and the ratio of axial compressibility is 2.50:1.26:1.00. A new monoclinic phase of TbPt assigned to the Pc or P2/c space group was observed at 32.5 GPa after laser heating at ∼1800 K. This new phase is stable at high pressure and presented a quenchable property on decompression to ambient conditions. The pressure–volume relationship is well described by the second-order Birch–Murnaghan equation of state, which yields V 0 = 672(4) Å3, = 123(6) GPa, which is about ∼14% more compressible than the orthorhombic TbPt. Our results provide more information on the structure and elastic property view, and thus a better understanding of the physical properties related to magnetic structure in some intermetallic rare earth alloys. (paper)
Source
Available from http://dx.doi.org/10.1088/1361-648X/aaaf9b; Country of input: International Atomic Energy Agency (IAEA)
Record Type
Journal Article
Journal
Country of publication
ANISOTROPY, COMPRESSIBILITY, COMPRESSION, DIAMONDS, ELASTICITY, EQUATIONS OF STATE, INTERMETALLIC COMPOUNDS, LASER-RADIATION HEATING, LATTICE PARAMETERS, MONOCLINIC LATTICES, ORTHORHOMBIC LATTICES, PHASE TRANSFORMATIONS, PHYSICAL PROPERTIES, PRESSURE RANGE GIGA PA, RARE EARTH ALLOYS, SPACE GROUPS, SYNCHROTRONS, X-RAY DIFFRACTION
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue