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Kannan, U.M; Narayana Jammalamadaka, S., E-mail: surya@iith.ac.in
Proceedings of the seventeenth international conference on thin films: abstracts2017
Proceedings of the seventeenth international conference on thin films: abstracts2017
AbstractAbstract
[en] We report on the magnetic effects on the solar cell efficiency of TiO2 based dye sensitized solar cells (DSSC). The strong spin orbit coupling of rare earth Ho3+ ions introduced by the addition of Ho2O3 into the photoanode resulted in a 13% enhancement in the power conversion efficiency of DSSC. Such an enhancement in the efficiency may be attributed to the improved lifetime of photo generated excitons as a result of the accelerated intersystem crossing phenomenon. This observation is supported by our photoluminescence (PL) measurements where we could observe a decrease in the photo emission intensity with the addition of Ho2O3. In addition, we have used a low magnetic field of 100 Oe to further enhance the overall efficiency to 6.06%, which in turn proves that the Lorentz force plays a significant role in magnetic field controlled charge transport in DSSC. Finally, we have carried out an electrochemical impedance measurement to determine the nature of charge transport within the devices. (author)
Source
CSIR-National Physical Laboratory, New Delhi (India); Indian Vacuum Society, Mumbai (India); 236 p; 2017; p. 158; ICTF-2017: 17. international conference on thin films; New Delhi (India); 13-17 Nov 2017
Record Type
Book
Literature Type
Conference
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ANODES, CHALCOGENIDES, COUPLING, DIRECT ENERGY CONVERTERS, ELECTRICAL PROPERTIES, ELECTRODES, EMISSION, EQUIPMENT, HOLMIUM COMPOUNDS, IMPEDANCE, INTERMEDIATE COUPLING, LUMINESCENCE, OXIDES, OXYGEN COMPOUNDS, PHOTOELECTRIC CELLS, PHOTON EMISSION, PHOTOVOLTAIC CELLS, PHYSICAL PROPERTIES, RARE EARTH COMPOUNDS, SOLAR EQUIPMENT, TITANIUM COMPOUNDS, TRANSITION ELEMENT COMPOUNDS
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