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Sachs, Malte; Bohnen, Kirsten; Conrad, Matthias; Klein, Benedikt P; Krug, Claudio K; Pietzonka, Clemens; Schmid, Martin; Zörb, Steffen; Gottfried, J Michael; Harbrecht, Bernd, E-mail: malte.sachs@chemie.uni-marburg.de2018
AbstractAbstract
[en] We investigated the compound 1T-CuxTa1−xS2 with respect to its synthesis, homogeneity range, structure and electronic properties. The average structure of 1T-CuxTa1−xS2 resembles that of the high-temperature phase of the layered transition metal dichalcogenide 1T-TaS2 in which tantalum is partially substituted by copper. 1T-CuxTa1−xS2 readily decomposes at elevated temperatures and can only be prepared and stabilized by a sufficiently high amount of sulfur excess. XPS and NEXAFS measurements reveal that copper has the oxidation state +I in 1T-CuxTa1−xS2, which is supported by quantum chemical calculations. The disorder introduced by copper doping causes an Anderson-type localization of the conduction electrons as manifested by a strong increase of the electrical resistivity and a Curie-type paramagnetism at low temperatures as in other doped systems 1T-M xTa1−xS2 with higher valent metals. Quantum chemical calculations support this interpretation. (paper)
Source
Available from http://dx.doi.org/10.1088/1361-648X/aad9c6; Country of input: International Atomic Energy Agency (IAEA)
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Journal Article
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CHALCOGENIDES, CHEMICAL REACTIONS, ELECTRICAL PROPERTIES, ELECTRON SPECTROSCOPY, ELEMENTS, MAGNETISM, MATERIALS, METALS, PHOTOELECTRON SPECTROSCOPY, PHYSICAL PROPERTIES, REFRACTORY METAL COMPOUNDS, REFRACTORY METALS, SPECTROSCOPY, SULFIDES, SULFUR COMPOUNDS, TANTALUM COMPOUNDS, TRANSITION ELEMENT COMPOUNDS, TRANSITION ELEMENTS
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