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AbstractAbstract
[en] The thin layer sectioning technique has been used in order to determine the solute diffusivity of 59Fe tracers in the light rare-earth metals cerium, praseodymium, and neodymium. The measurements were made both in the close-packed (fcc for Ce and double-hcp for Pr and Nd) and in the high-temperature bcc phases of the solvent metals. The diffusivities of iron are extremely high, with values exceeding 10-5 cm2/sec at temperatures above 0.7 T/sub m/ (T/sub m/ melting temperature of the solvent metal). The activation energies are much lower than the activation energy for self-diffusion, of the order of 10 kcal/mole. The results indicate that iron is a fast-diffusing solute, its diffusion in the rare-earth metals taking place probably by means of the dissociative mechanism, with a predominantly interstitial component. Several simultaneous measurements of the diffusivity of 54Mn suggest that Mn is also a fast-diffusing solute, though to a lesser extent than 59Fe. (U.S.)
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Record Type
Journal Article
Journal
Acta Metallurgica; v. 23(4); p. 473-479
Country of publication
BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, CRYSTAL DEFECTS, CRYSTAL LATTICES, CRYSTAL STRUCTURE, CUBIC LATTICES, DAYS LIVING RADIOISOTOPES, ELECTRON CAPTURE RADIOISOTOPES, ELEMENTS, ENERGY, EVEN-ODD NUCLEI, HEXAGONAL LATTICES, INTERMEDIATE MASS NUCLEI, IRON ISOTOPES, ISOTOPE APPLICATIONS, ISOTOPES, MANGANESE ISOTOPES, METALS, NUCLEI, ODD-ODD NUCLEI, POINT DEFECTS, RADIOISOTOPES, RARE EARTHS, TRANSITION ELEMENTS
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