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AbstractAbstract
[en] Absolute rate constants for the reaction of OH radicals with H2 and NO (M = Ar, N2) have been determined at 298 +- 10K using a flash photolysis-resonance fluorescence technique. The rate constant for the reaction OH + H2 was determined to be (6.97 +- 0.70) x 10-15 cm3 molecule-1 sec-1 in good agreement with recent literature values. Rate constants for the reaction OH + NO + M (M = Ar) were obtained over the pressure region 26-655 torr, while a rate constant for M = N2 was obtained at 25 torr total pressure. The low pressure third order rate constants for this reaction were determined to be (4.25 +- 0.43) x 10-31 cm6 molecule-2 sec-1 (M = Ar) and (6.1 +- 0.7) x 10-10 cm6 molecule-2 sec-1 (M = N2), in good agreement with the available literature values. The bimolecular rate constants at 760 torr total pressure were determined to be (5.2 +- 0.8) x 10-12 cm3 molecule-1 sec-1 for M = Ar and (6.1 +- 1.0) x 10-12 cm3 molecule-1 sec-1 for M = N2. A value of 8 x 10-12 cm3 molecule-1 sec-1 was obtained as a probable lower limit for the limiting high pressure second order rate constant from an extrapolation of the data. (U.S.)
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Journal Article
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Journal of Chemical Physics; v. 62(8); p. 3284-3288
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