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AbstractAbstract
[en] Extraction of indium from H2SO4 and KBr solution in the form of bromoindate brilliant green diminishes in the presence of relatively large amounts of such metals being extracted as Fe(3), Tl(3), Zn, Hg(2) and Cd. Gallium has no effect on the extraction of indium. With the use of radioactive isotope sup114m in the influence of the medium acidity, of the concentration of metals and of the nature of organic solvent on the extent of indium extraction inhibition in the presence of macroelements has been studied. The character and extent of inhibition of indium extraction depend on the nature of the macroelement: the better the macroelement can be extracted in the form of an ion association, the stronger it inhibits the extraction of indium. Inhibition of the extraction is explained by dissociation of the ion associations extracted in the organic phase and, as a consequence of this dissociation, by the action of the common ion, vix., the dye cation
Original Title
Podavlenie ehkstraktsii bromindata brilliantovogo zelenogo v prisutstvii postoronnikh metallov; Foreign metals are Ga, Fe(3), Cd, Zn, Hg, i Tl(3)
Primary Subject
Source
For English translation see the journal J. Anal. Chem. USSR.
Record Type
Journal Article
Journal
Zhurnal Analiticheskoj Khimii; v. 30(9); p. 1692-1696
Country of publication
ALKALI METAL COMPOUNDS, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, BETA-PLUS DECAY RADIOISOTOPES, BROMIDES, BROMINE COMPOUNDS, COMPLEXES, DAYS LIVING RADIOISOTOPES, ELECTRON CAPTURE RADIOISOTOPES, HALIDES, HALOGEN COMPOUNDS, HYDROGEN COMPOUNDS, INDIUM ISOTOPES, INORGANIC ACIDS, INTERMEDIATE MASS NUCLEI, ISOMERIC TRANSITION ISOTOPES, ISOTOPES, NUCLEI, ODD-ODD NUCLEI, OXYGEN COMPOUNDS, POTASSIUM COMPOUNDS, RADIOISOTOPES, SECONDS LIVING RADIOISOTOPES, SEPARATION PROCESSES, SULFUR COMPOUNDS
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