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AbstractAbstract
[en] Crystals of Te3Cl2, within the isotypic series Te2X (X=Cl, Br, I) of Te2Br and Te2I, as well as of β-TeI and α-TeI have been prepared and were used for structure determination with single crystal methods. Te3Cl2 is monoclinic, space group P21/n, z=4, with a=10.136(15), b=8.635(3), c=7.039(8) A and β=100.74(6)0. The structure consists of macromolecular units of tellurium atoms, which relation to the structure of elemental tellurium is discussed. Te2X is orthorhombic with space group Pnam, z=8. Lattice parameters for the bromide [iodide] are:a=14.921(12) [15.295(3)], b=12.843(6) [13.694(4)], c=4.005(3) [4.123(2)] A. The structure consists of infinite double chains condensed to ribbons of Te6 rings with boat conformation and bridging halogen atoms at the edges. β-TeI is monoclinic, space group C2/m, z=8, with cell constants a=15.383(2), b=4.182(2), c=11.999(2) A and β=128.09(1)0. The structure consists of endless chains of tellurium atoms along which the iodine atoms occupy alternating bridging and terminal positions. α-TeI is triclinic, space group P1, z=8, with lattice parameters a=9.958(3), b=7.992(2), c=8.212(4) A, α=104.37(11), β=90.13(4) and γ=102.89(7)0. The macromolecular building principle of the subhalides of tellurium is degenerated in α-TeI to a Te4-ring (the Te4I4 molecule). The structures studied are compared to each other and discussed in connection with structures of other tellurium compounds. (author)
Original Title
Zur Kenntnis der Subhalogenide des Tellurs
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Record Type
Journal Article
Journal
Z. Anorg. Allg. Chem; v. 422(1); p. 17-38
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