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AbstractAbstract
[en] The heat capacities of Nb3Al, Nb3Sn, and Nb3Sb were measured between 2 and 400 K. Their superconducting transition temperatures T/subc/ are 18.5, 17.9, and 0.2 K, respectively. The higher-temperature entropy was analyzed, and it was found that phonon-mode softening occurs on cooling for the two high-T/subc/ compounds but not for Nb3Sb. Geometric mean phonon frequencies ω/subg/ are also evaluated for these compounds and for V3X, where X = Si, Ga, Ga0.5Sn0.5, and Sn. As is shown, ω/subg/ is an appropriate phonon average for evaluating McMillan's expression for the electron-phonon mass enhancement. Average phonon properties cannot reliably be used to calculate T/subc/ values for these A-15 materials. It is suggested that, for the higher electronic density-of-states materials, select phonon modes strongly couple to the electronic system and influence the magnitude of T/subc/ to a greater extent than average-phonon correlations would indicate. This view is supported by the observation that the higher-density-of-states materials exhibit the more pronounced phonon-mode softening on cooling
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Phys. Rev., B; v. 13(9); p. 3783-3789
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