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AbstractAbstract
[en] The hydriding properties of Nb--Pd and Nb--Rh alloys were investigated. Results show that hydrogen uptake under retention of the body centered cubic structure, characteristic of VB and VIB metals, can raise T/sub c/. This is the case for both the original Nb0.8Pd0.2H0.39 as well as Nb0.8Rh0.2H0.10. The situation is less clear in the case of the aged hydride of Nb0.8Pd0.2. So far hydrogen take up either in Nb as well as compounds such as Nb3Sn has been proven to be deleterious to superconductivity. The increases of T/sub c/ upon hydriding of Nb--Pd and Nb--Rh alloys can, among other factors, be explained in a straightforward fashion on the basis of lattice parameter. Alloying Nb with Rh decreases the lattice parameter of Nb as well as T/sub c/. Hydriding increases the lattice parameters again. The concomitant increase in T/sub c/ should then not be surprising as it reestablishes the original spacial situation. A similar situation holds concerning straightforward electron rules. However, beyond simple spatial and electronic arguments there will certainly be some electronic rearrangements and modifications in bonding which will have a decisive influence on superconductivity. In fact a relation can be expected to the respectable superconducting transition temperatures found in a variety of metastable compounds between Nb and noble metals at relatively high Nb concentrations. Results of the study open the possibility of achieving high values of T/sub c/ by modifying lattice parameters and electronic structure via the introduction of hydrogen
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Journal of Solid State Chemistry; v. 17(4); p. 443-445
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