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AbstractAbstract
[en] Rate coefficients for the excitation of the 4.3-μm bands of CO2 by low-energy electrons in CO2 have been measured using a drift-tube technique. The CO2 density [(1.5 to 7) x 1017 molecules/cm3] was chosen to maximize the radiation reaching the detector. Line-by-line transmission calculations were used to take into account the absorption of 4.3-μm radiation. A small fraction of the approximately 10-8 W of the 4.3-μm radiation produced by the approximately 10-7-A electron current was incident on an InSb photovoltaic detector. The detector calibration and absorption calculations were checked by measuring the readily calculated excitation coefficients for vibrational excitation of N2 containing a small concentration of CO2. For pure CO2 the number of molecules capable of emitting 4.3-μm radiation produced per cm of electron drift and per CO2 molecule varied from 10-17 cm-2 at E/N = 6 x 10-17 V cm2 to 5.4 x 10-16 cm-2 at E/N = 4 x 10-16 V cm2. Here E is the electric field and N is total gas density. The excitation coefficients at lower E/N are much larger than estimated previously. A set of vibrational excitation cross sections is obtained for CO2 which is consistent with the excitation coefficient data and with most of the published electron-beam data
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Physical Review. A; v. 14(2); p. 615-629
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