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AbstractAbstract
[en] From a set of critically selected literary data on the emf's of concentration cells consisting of sodium metal and sodium amalgam in a sodium salt non-aqueous electrolyte a value of E0sub(Na(Hg)/Na+) = -1.95584 V was calculated for the standard equilibrium potential of diluted liquid sodium amalgam at 250C. The standard state of the amalgam was derived from an amalgam at infinite dilution where fsub(Na)→ 1.0 for xsub(Na)→ 0. The activity coefficient of sodium in the amalgam at an arbitrary composition, corresponding to this standard state, is obtained from the expression 1g fsub(Na(Hg)) = 16.393 xsub(Na). (author)
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Electrochimica Acta; v. 21(11); p. 953-956
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