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AbstractAbstract
[en] Using the diabatic ground state H+3 surface given in analytic form by Giese and Gentry, a coupled-states study of the rotational excitation of H2 (taken as a rigid rotor) by proton impact is made at 3.7 eV. Transitions 0→j', with j'=0,2,4,...,26, are considered, and one finds a broad distribution in final rotor state j' which is consistent with recent beam experiments. Despite long-range rotational coupling produced by the charge-quadrupole interaction, the coupled-states method gives a good description of the rotational excitation process as is demonstrated by comparison to standard close-coupling cross sections. Intermultiplet transitions (neglected in the coupled-states approximations) are shown to be less important in the high energy limit
Original Title
Rotational excitation, coupling, diabatic ground state H3+
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Record Type
Journal Article
Journal
Journal of Chemical Physics; v. 65(8); p. 3275-3279
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