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AbstractAbstract
[en] The ternary diagram of the amorphous phase in the splat-cooled Fe--P--B system was investigated by x-ray diffraction measurements. Alloys were found to be amorphous within the Fe concentration range 75 less than or equal to c/sub Fe/ less than or equal to 83 at. percent. For a fixed Fe concentration, B substitutes for P over a large scale, the maximum substitution occurring for c/sub Fe/ = 80 at. percent. Concentration dependence of the electronic and magnetic properties was systematically studied in alloys within the whole amorphous diagram by means of bulk magnetization, anti μ (4.20K), Curie temperature, T/sub c/, and electrical resistivity, rho, measurements from 4.20K up to the amorphous-crystal transformation. The composition dependence of anti μ and T/sub c/ when B substitutes for P at c/sub Fe/ constant suggests the existence of two different short-range orders in the amorphous alloys, corresponding to the epsilon and epsilon1 crystal structures in the Fe3P/sub 1-x/B/sub x/ compounds. The concentration dependence of anti μ and T/sub c/ when P (or B) substitutes for Fe at c/sub B/ (or c/sub P/) constant is explained by a comparison between the amorphous Fe and the fcc Fe. A minimum in the variation of rho as a function of the temperature T occurs at T/sub m/. The temperature dependence of rho is expressed by a phenomenological law: rho(T) = rho0 + A log T + B T2 + CT. The concentration dependence of T/sub m/ and of the coefficients A and B is discussed in relation with the magnetic and structural properties of the amorphous Fe--P--B alloys. 10 figures, 1 table
Original Title
75 to 83 at.% Fe
Primary Subject
Source
Nov 1976; 27 p; Available from NTIS., PC A03/MF A01
Record Type
Report
Report Number
Country of publication
AMORPHOUS STATE, BORON COMPOUNDS, CHEMICAL COMPOSITION, CURIE POINT, ELECTRIC CONDUCTIVITY, IRON BASE ALLOYS, LOW TEMPERATURE, MAGNETIC MOMENTS, MAGNETIC PROPERTIES, MAGNETIZATION, MEDIUM TEMPERATURE, PHOSPHORUS COMPOUNDS, SPLAT COOLING, TEMPERATURE DEPENDENCE, TERNARY ALLOY SYSTEMS, ULTRALOW TEMPERATURE, VERY LOW TEMPERATURE
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