Filters
Results 1 - 1 of 1
Results 1 - 1 of 1.
Search took: 0.015 seconds
Zemke, W.T.; Crooks, J.B.; Stwalley, W.C.
Wartburg Coll., Waverley, Iowa (USA). Dept. of Chemistry; Iowa Univ., Iowa City (USA). Dept. of Chemistry1977
Wartburg Coll., Waverley, Iowa (USA). Dept. of Chemistry; Iowa Univ., Iowa City (USA). Dept. of Chemistry1977
AbstractAbstract
[en] Newly calculated radiative transition probabilities for the A 1Σ+ → X 1Σ+ (v' -v'') emission bands of 7LiH re used to calculate the radiative lifetime of the various vibrational levels (0 < or = v' < or = 26) of A 1Σ+ LiH. For higher levels, an estimate of the bound-to-free emission probability is also needed and included. For the highest two levels, A 1Σ+ → B 1PI emission is possible and has been included, but makes a negligible contribution to the radiative lifetime. The calculated radiative lifetimes increase with v' from 28.9 nsec at v' = 0 to 36.1 nsec at v' = 16 and then decrease to 27.1 nsec at v' = 26. They are found to be in good agreement with measured total lifetimes, implying the nonradiative (predissociative) lifetime for the measured levels is approximately > 10-7 seconds, in accord with simple theoretical expectations
Original Title
Transition probabilities
Primary Subject
Source
1977; 14 p; Available from NTIS., PC A02/MF A01
Record Type
Report
Report Number
Country of publication
Reference NumberReference Number
INIS VolumeINIS Volume
INIS IssueINIS Issue