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[en] Highlights: • Wear rate of nitrided HEAs was lower than that of as-cast HEAs in the same condition. • The wear mechanism of as-cast alloys in air was abrasive wear of oxide particles. • The wear mechanism of the nitrided HEAs in air was adhesive wear and abrasive wear. • The wear mechanism of HEAs in acid rain was abrasive, oxidative and corrosive wear. • The lubrication action of deionized water and acid rain led to the lower wear rate.