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AbstractAbstract
[en] Sm-Nd-isotopic-geochronologic data are obtained on the time of formation of metamorphic paragenesis of minerals sampled from four kimberlites in Yakutia. It is shown that the studied complex of rocks mainly corresponds to plagiogneisses of average composition in terms of mineral associations, chemical composition and metamorphism parameters. The ancient estimates of Nd-model age of xemolites (2.9-3.3 billion years) are comparable with those of metadeposits of the Daldyn series of the Anabar shield
Original Title
Sm-Nd-izotopnye sistemy v nizhnekorovykh ksenolitakh iz kimberlitov Yakutii
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 327(3); p. 374-378
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[en] Unstability of argon (40Ar/38Ar) and carbon isotope ratio of CO2 and CH4 in gases carried out from opened well (the depth is 1000 m) on surface with mineral water, is considered in detail. The well is laid on Gelli-Paraul region hopeless to petroleum and gas
Original Title
O vremennykh nestabil'nostyakh izotopnogo sostava argona i ugleroda CO2 i CH4 v vodno-gazovykh sistemakh struktury Gellii-Paraul (Dagestanskij klin)
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 330(6); p. 767-770
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[en] Construction of consistent asymptotics of Schroedinger equation was conducted. The equation solution was derived with the use of a new method, enabling to perform expansions in terms of 1/N powers
Original Title
Novyj asimptoticheskij metod integrirovaniya uravnenij kvantovoj mekhaniki pri nalichii sil'noj svyazi
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Journal Article
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 328(5); p. 557-558
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AbstractAbstract
[en] Results of X-ray diffraction analysis of mixed-valence tetranuclear vanadium (V2, V3) complex, isolated from nitrogen fixing system are given. Crystals of mixed-valence vanadium (V2, V3) complex are monoclinic, at 140 K: a = 16.748(7), b 16.959(8), c = 21.764(9) A, β = 109.53(3) deg, V = 5655(2) A, Z = 2, sp.gr.P 21/n
Original Title
Struktura smeshannovalentnogo chetyrekh''yadernogo kompleksa (V2, V3), vydelennogo iz sistemy V2-3,5-ditret.-butilpirokatekhin-NaOCH3, vosstanavlivayushchej molekulyarnyj azot v metanole
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Journal Article
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 328(5); p. 585-588
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AbstractAbstract
[en] A study was made on the effect of alloying type of Fe-P alloys on peculiarities of structural transformations in amorphous alloys (AA) of Fe-P-Mn, Fe-P-Si ternary systems and Fe-P-Mn-V quaternary system. It is shown that character of phase equilibrium in Fe-P-M systems can change the degree of alloying element effect on phosphorus segregation in alloys with formation of various metastable phases with phosphorus participation processes of alloying element redistribution, taking place in surface AA layers, lead to formation of one or another metastable phase with higher phosphorus content, as compared to equilibrium phases
Original Title
Messbauehrovskoe issledovanie protsessov segregatsii i strukturnykh prevrashchenij v amorfnykh splavakh sistem Fe-P-M (M:Mn, Si, V)
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Journal Article
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 328(5); p. 575-579
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[en] A study was made on the influence of effective electron acceptor-oxopiperidine cation, immobilized of the surface of micelle anion surfactants, on luminescence quenching of tristipyridyl ruthenium complex. It was revealed that this method enabled to determine reliably the critical concentration of micelle formation of anion surfactants
Original Title
Tushenie lyuminestsentsii trisdipiridil'nogo kompleksa ruteniya oksopiperidinievym kationom v rastvorakh dodetsilsul'fata natriya i aehrozolya OT
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 328(5); p. 589-591
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[en] The diffusion of labelled oxygen (O18) atoms in Bi2Sr2CaCu2O8 high-tc superconductors was studied. The temperature dependences (494-573 K) of oxygen atom diffusion coefficients in polycrystalline Bi2Sr2CaCu2O8 and YBa2Cu3O7-δ were given. An universal character of the diffusion mechanism in high-tc superconductors with quasi-plane structure was noted
Original Title
Diffuziya mechenykh atomov kisloroda v Bi2Sr2CaCu2O8
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 328(2); p. 190-192
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ALKALINE EARTH METAL COMPOUNDS, BISMUTH COMPOUNDS, CALCIUM COMPOUNDS, CHALCOGENIDES, COPPER COMPOUNDS, EVEN-EVEN NUCLEI, ISOTOPES, LIGHT NUCLEI, NUCLEI, OXIDES, OXYGEN COMPOUNDS, OXYGEN ISOTOPES, STABLE ISOTOPES, STRONTIUM COMPOUNDS, SUPERCONDUCTORS, TEMPERATURE RANGE, TRANSITION ELEMENT COMPOUNDS, YTTRIUM COMPOUNDS
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[en] Kinetic and stationary methods were used to study luminescence quenching of trisbipiridine ruthenium complex in aqueous-micellar solution of cetyltrimethylammonium bromide by several quenchers of different hydrophilic-lipophilic nature. 13 refs., 2 figs., 2 tabs
Original Title
Tushenie lyuminestsentsii trisbipiridil'nogo rutenievogo kompleksa v mitsellyarnoj sisteme. Vliyanie prirody tushitelya
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Journal Article
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 328(1); p. 66-71
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AbstractAbstract
[en] Equations permitting evaluation of metal-hydrogen binding energy for metals with dose-packed and body-centered crystal lattices on the basis of the L. Pauling ratio were suggested. The values of metal crystal lattice energy (Ecr) and difference in the values of hydrogen and metal electronegativity are used in the calculations. The equations derived also permit evaluating electrochemical characteristics of the metals, equilibrium potential of hydrogen ion discharge on metal, as regards hydrogen electrode, and potential of zero charge as Ecr function, in particular. A satisfactory agreement between calculated and experimental data suggests correctness of the equations mentioned
Original Title
Otsenka velichiny ehnergii svyazi metall-vodorod
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 326(2); p. 300-304
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[en] Palladium-catalyzed arylation of water-soluble olefins by arylhalides (Heck reaction) is described. Styrene reacts with aryliodides at 100 deg in Na2CO3 or K2CO3 aqueous solution during Pd(OAc)2 catalysis in the presence of small amount of Bu3N with formation of substituted stilbenes
Original Title
Kataliziruemoe palladiem arilirovanie stirola v vode
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Doklady Akademii Nauk - Rossijskaya Akademiya Nauk; CODEN DAKNEQ; v. 332(4); p. 454-456
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ALKALI METAL COMPOUNDS, ALKYLATED AROMATICS, AROMATICS, CARBON COMPOUNDS, CARBONATES, CHEMICAL REACTIONS, DISPERSIONS, HOMOGENEOUS MIXTURES, HYDROCARBONS, KINETICS, MIXTURES, ORGANIC COMPOUNDS, ORGANIC HALOGEN COMPOUNDS, OXYGEN COMPOUNDS, POTASSIUM COMPOUNDS, REACTION KINETICS, SOLUTIONS, TRANSITION ELEMENT COMPOUNDS
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