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[en] Newly calculated radiative transition probabilities for the B 1Pi→X 1Σ+ and A 1Σ+ emission bands of 7LiH (preceding paper) are used to calculate the radiative lifetime of the various vibrational levels (0< or =v'< or =2) of B 1Pi LiH. An estimate of the B→X bound--free emission probability is also included, although the lifetimes are dominated by the B→X bound--bound emission. The calculated radiative lifetimes increase rapidly with v' from 11.3 nsec at v'=0 to 17.0 nsec at v'=1 and then 24.0 nsec at v'=2
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Journal Article
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Journal of Chemical Physics; v. 69(1); p. 409-410
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[en] The total photoionization cross section of the 1s level of nitrogen in N2 and N2O molecules has been measured using monochromatized synchrotron radiation. High-resolution spectra in the range 390 < h ω < 450 eV were recorded. A broadband in the continuum at 9.4 eV above the ionization threshold, due to the f-type shape resonance, has been measured with high resolution. The data are compared with theoretical calculations of photoionization cross section. Recent Hartree-Fock calculations in the static-exchange approximation agree better than earlier results, which employed the multiple-scattering method
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Journal Article
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Physical Review. A; v. 17(6); p. 1907-1911
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[en] Fundamental T (ν3) type high-J rovibrational fine structure is derived for a range of values of the Coriolis and [2 x 2]4 centrifugal constants. The theory of level clusters is developed further. Correlations are made between cluster states corresponding to well separated P+, Q0, and R- branches, and the opposite case in which Pi/sub plus-or-minus/ and Σ0 labels are appropriate
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Journal of Chemical Physics; v. 69(11); p. 4896-4907
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[en] We have calculated the photoionization cross section for the (1s22s22p53s)3P metastable state of neon using ab initio, many-electron wave functions in the LS-coupling scheme. We have considered all the channels which arise from the (1s22s22p5)2P state of Ne+ and an ejected p electron. The continuum was made discrete by approximating the final states as superpositions of square-integrable configurations. The Stieltjes moment-theory technique was used to construct the continuum oscillator strength distribution. Both the dipole-length and the dipole-velocity forms of the cross section were evaluated. We have examined systematically the effects of orbital relaxation, core polarization, and electron correlation and found them to be important within 5 eV of threshold. The peak value of the photoionization cross section for metastable Ne is 1.9 x 10-19 cm2, which is much smaller than the corresponding value for the ground state. We have also calculated the line strengths for a few bound-bound transitions as well as the static polarizability of the 3P metastable state
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Physical Review. A; v. 16(6); p. 2376-2387
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[en] Multiphoton dissociation of various halogenated hydrocarbons by laser beams is reported. The statistical theory of unimolecular reactive is found to be adequate to explain the process
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Journal of Chemical Physics; v. 68(3); p. 1306-1307
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[en] N2 and O2 broadened linewidths of HNO3 at 3000K have been computed for about 1500 transitions of a- and c-type and for about 2500 transitions of b-type
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Journal of Chemical Physics; v. 68(4); p. 2012-2013
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[en] A knowledge of the properties of small metal particles is essential to the understanding of catalysis on a molecular level. In this regard, one particularly important property is the rate at which the dissociation energy of a small metal cluster approaches the bulk cohesive energy. The present research concerns the effect of electron correlation on the dissociation energy of a particularly stable beryllium cluster, the tetrahedral Be4 system. A contracted Gaussian basis set of size Be(9s 4p/5s 2p) was adopted in conjunction with the recently developed theory of self-consistent electron pairs (SCEP). Several new theoretical and computational wrinkles are discussed, including the incorporation of the SCEP/coupled electron pair approximation (SCEP/CEPA). The Be4 results provide strong evidence for the reliability of the Hartree--Fock approximation for alkaline earth cohesive energies. As suggested earlier the Be4 dissociation energy appears to be approx.40 kcal/mole. Analogous studies of the Be2 molecule are reported
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Journal of Chemical Physics; v. 65(12); p. 5141-5146
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Seminar on unsolved problems in physics; Bangalore, India; 17 Jul 1972; 22 refs.
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Proc. Indian Acad. Sci., Sect. A; v. 78(1); p. 13-24
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[en] The A--X band of gaseous UF6 has been studied using the laser-induced fluorescence technique. Excitation and fluorescence spectra are presented for various pressures of UH6 at room temperature. The fluorescence spectra show little change over the pressure range 0.2--20 torr, with a peak wavelength at 421 nm. In contrast, the peak wavelength of the excitation spectra shows a noticeable shift from 391 to 385 nm when the UF6 pressure is increased from 2 to 20 torr. A Stern--Volmer plot of UF6 self-quenching data shows a pronounced nonlinear behavior over this same pressure region. From an analysis of the laser-induced fluorescence spectra, we develop a simple kinetic model for UF6 excited- state dynamics. A standard kinetic treatment of this scheme yields a prediction for the dependence of the fluorescence decay lifetime on total pressure that is in good agreement with experimental results
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Journal of Chemical Physics; v. 69(5); p. 2181-2187
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[en] A remarkable improvement of both intelligibility and naturalness of infinitely clipped speech can be achieved by means of a multichannel system in which the speech signal is splitted into several band-pass channels before the clipping and successively reconstructed by summing up the clipped outputs of each channel. A possible explanation of such an improvement is given, founded on the so-called zero-based representation of band limited signals where the zero-crossings sequence is considered as a set of samples of the signal
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