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AbstractAbstract
No abstract available
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6 figs.; 1 tab.; 13 refs.
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Journal Article
Journal
Berichte der Bunsengesellschaft fuer Physikalische Chemie; v. 77(1); p. 48-52
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AbstractAbstract
No abstract available
Original Title
Synthese von Verbindungen des Scandiums und des Yttriums mit Hydrazido-Kohlensaeure
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Journal Article
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Monatshefte fuer Chemie; v. 103(6); p. 1572-1574
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AbstractAbstract
No abstract available
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5 tabs.; 17 refs.
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Journal Article
Journal
Zeitschrift fuer Physikalische Chemie (Frankfurt); v. 81(5/6); p. 286-293
Country of publication
AGAR, CALCIUM 45, CALCIUM CHLORIDES, CESIUM 137, CESIUM CHLORIDES, DIFFUSION, ELECTROLYTES, ERRORS, GELS, MEDIUM TEMPERATURE, ONSAGER RELATIONS, QUANTITATIVE CHEMICAL ANALYSIS, QUANTITY RATIO, RADIONUCLIDE MIGRATION, SODIUM 22, SODIUM CHLORIDES, SOLUTIONS, SOLVATION, STRONTIUM 89, STRONTIUM CHLORIDES, TRACER TECHNIQUES, ZONES
ALKALI METAL COMPOUNDS, ALKALINE EARTH METAL COMPOUNDS, BETA DECAY RADIOISOTOPES, BETA-MINUS DECAY RADIOISOTOPES, BETA-PLUS DECAY RADIOISOTOPES, CALCIUM COMPOUNDS, CALCIUM ISOTOPES, CARBOHYDRATES, CESIUM COMPOUNDS, CESIUM ISOTOPES, CHEMICAL ANALYSIS, CHLORIDES, COLLOIDS, DAYS LIVING RADIOISOTOPES, DISPERSIONS, EVEN-ODD NUCLEI, HALIDES, INTERMEDIATE MASS NUCLEI, ISOTOPE APPLICATIONS, ISOTOPES, LIGHT NUCLEI, MIXTURES, NUCLEI, ODD-EVEN NUCLEI, ODD-ODD NUCLEI, ORGANIC COMPOUNDS, POLYSACCHARIDES, RADIOISOTOPES, SACCHARIDES, SODIUM COMPOUNDS, SODIUM ISOTOPES, STRONTIUM COMPOUNDS, STRONTIUM ISOTOPES, YEARS LIVING RADIOISOTOPES
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AbstractAbstract
No abstract available
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8 refs. Mound Laboratory is operated by Monsanto Research Corporation for the U.S.A.E.C. under contract No. AT-33-1-GEN-53.
Record Type
Journal Article
Journal
Radiochemical and Radioanalytical Letters; v. 9(5-6); p. 315-320
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AbstractAbstract
No abstract available
Original Title
K voprosu o polozhenii transaktinievykh ehlementov v periodicheskoj sisteme D.I. Mendeleeva
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Secondary Subject
Source
For English translation see the journal Sov. Radiochem.
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Journal Article
Journal
Radiokhimiya; v. 14(4); p. 618-622
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AbstractAbstract
[en] Experimental data are analysed concerning the influence of specific interaction of the solvent (water, acetonitrile (AN), dimethyl sulphoxide (DMSO) with the electrode (eutectic alloy of indium with gallium) on the adsorption (I-, Br-)). Specific interaction of solvents with the electrode increases in the sequence AN< H2O< DMSO. Stronger interaction of the alloy with DMSO diminishes the adsorption of various substances from DMSO. In AN, because of weakening of the specific interaction and diminishing of the solvation energy of the anions, the adsorption of I- anions increases as one goes from H2O over to AN. On the In-Ga alloys the value Δpsisub(Q=0)sup(Isup(-))=0.44 V. Thus, specific interaction of the solvent with the metal is accompanied by changes in the differential capacity of the binary electric layer, in the zero charge potential and in the adsorption properties of the electrode
Original Title
O vliyanii spetsificheskogo vzaimodejstviya rastvoritelya s metallom ehlektroda na stroenie dvojnogo ehlektricheskogo sloya i adsorbtsiyu
Primary Subject
Source
For English translation see the journal Sov. Electrochem.
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Journal Article
Journal
Ehlektrokhimiya; v. 13(6); p. 794-798
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Belov, S.F.; Durinin, E.V.
6. all-union conference on physical chemistry of ionic melts and solid electrolytes. Part 11976
6. all-union conference on physical chemistry of ionic melts and solid electrolytes. Part 11976
AbstractAbstract
No abstract available
Original Title
Issledovanie vzaimodejstviya (rastvorimosti) nekotorykh okislov vo ftortsirkonate kaliya; Oxides: ZrO2, La2O3, CeO2, CaO, CdO
Primary Subject
Source
AN SSSR, Moscow. Nauchnyj Sovet po Fizicheskoj Khimii Ionnykh Rasplavov i Tverdykh Ehlektrolitov; AN Ukrainskoj SSR, Kiev. Inst. Obshchej i Neorganicheskoj Khimii; p. 92-93; 1976; 6. all-union conference on physical chemistry of ionic melts and solid electrolytes; Kiev, Ukrainian SSR; Sep 1976; Published in summary form only.
Record Type
Miscellaneous
Literature Type
Conference
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AbstractAbstract
[en] Using the method of NMR19F, the solvolytic reactions are studied of tungsten hexafluoride with urea, thiourea, and guanidine. The reactions of WF6 with (NH2)2CO, (NH2)2CS, and (NH2)2CNHxHCl in acetonitrile result in the formation of anion [WF5N(NH2)CO]-, [WF5N(NH2)CS]- and molecular WF5NC(NH2)2 complexes containing the multiple bond W=NR. The compounds [NH3NH2CO][WF5N(NH2)CO] and WF5NC(NH2)2 are isolated in the solid form. On the basis of the dependence of the chemical shifts of the equatorial atoms of fluorine in related hexacoordination complexes of tungsten on the π-donor properties of short-bond nitrogen-containing ligands, a series of ligands is proposed in the order of decrease of their π-donor properties
Original Title
Mochevina, tiomochevina i guanidin - kratnosvyazannye ligandy v kompleksakh d0-ehlementov
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Journal Article
Journal
Koordinatsionnaya Khimiya; v. 3(5); p. 625-629
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AbstractAbstract
[en] Phase equilibrium in the systems WCl5-WCl6 and WCl5-WOCl4 have been studied by differential thermal and X-ray phase analyses. The components form the fusibility diagrams of the eutectic type. Eutectics melt at 190+-2 deg C and 200+-2 deg C; they contain 82 and 60 mol.% of WCl5, respectively. Oxotetrachloride and dioxodichloride of tungsten are formed in the system WCl6-WO3; no other phases are observed in the system. In the system WO2-WO2Cl2 the interaction of the components has not been observed up to 300 deg C. In the ternary system WCl5-WOCl4-WCl6 the ternary eutectics melt at 180+-3 deg C and contain 60 mol.% of WCl5, 22 mol.% of WOCl4, and 18 mol.% of WCl6
Original Title
Fazovye ravnovesiya v sisteme vol'fram-khlor-kislorod
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Source
5 refs.; for English translation see the journal Russ. J. Inorg. Chem.
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Journal Article
Journal
Zhurnal Neorganicheskoj Khimii; v. 22(7); p. 1956-1960
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AbstractAbstract
No abstract available
Original Title
Sistema khlorid tseriya-khlorid ehtanolamina-voda pri 50 i 25 deg C
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Source
6 refs.; published in summary form only; for English translation see the journal Russ. J. Inorg. Chem.
Record Type
Journal Article
Journal
Zhurnal Neorganicheskoj Khimii; v. 22(7); p. 2019-2021
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